Two New Coordination Complexes Based on Eosin Y Dye Ligand: Syntheses, Crystal Structures and Magnetic Properties

被引：3

作者：

Xu Xiao-Wu ^{[1
,2
]}

Zhou Zhong-Yuan ^{[1
]}

Tian Chong-Bin ^{[1
]}

Du Shao-Wu ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[2] Grad Univ Chinese Acad Sci, Beijing 100039, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 36卷 / 10期

基金：

中国国家自然科学基金;

关键词：

coordination compounds; solvothermal reactions; Eosin Y dye; antiferromagnetic couplings; VISIBLE-LIGHT; IRRADIATION; FRAMEWORKS; HYDROGEN;

D O I：

10.14102/j.cnki.0254-5861.2011-1573

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel coordination compounds formulated as [Co-2(EY)(2)(L-1)]center dot 2C(2)H(5)OH (1) and [Mn-2(EY)(2)(L-1)]center dot 2C(2)H(5)OH (2) (EY = Eosin Y dianion, L-1 = 4,4'-bipyridine) based on Eosin Y dye ligand have been prepared by solvothermal reactions and structurally characterized. Single-crystal X-ray diffraction studies reveal that compounds 1 and 2 are isostructural. They show weak antiferromagnetic coupling between the adjacent Co-II and Mn-II ions, respectively.

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页码：1593 / 1600

页数：8

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