Synthesis and characterisation of mixed dithiolatoarsenic(III) alkyldithiocarbonates and dialkyldithiocarbamates

被引：0

作者：

Chauhan, HPS ^{[1
]}

Chourasia, S ^{[1
]}

Nahar, B ^{[1
]}

Singh, RK ^{[1
]}

机构：

[1] Devi Ahilya Univ, Inst Chem Sci, Indore 452001, Madhya Pradesh, India

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1998年 / 134卷

关键词：

dithiolatoarsenic; dithiocarbamates; dithiocarbonates; IR spectra; NMR spectra;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mixed dithiolatoarsenic (III) alkyldithiocarbonate and dialkyldithiocarbamate derivatives of the type SCH2CH2SAs(S2COR), [where R = Et, Pr-n, Pr-i, Bu-n & Bu-i] and SCH2CH2SAs(S2CX), [where X = NMe2, NEt2 and N(CH2CH2)(2)] are reported. These are synthesised by the simple replacement reactions of 2-chloro-1,3-dithia-2-arsacyclopentane with potassium alkylxanthate and with sodium dialkyldithiocarbamate in 1:1 molar ratios in benzene respectively. These derivatives have been characterised by elemental analyses, melting point determinations as well as IR & NMR (H-1 and C-13) spectral studies and tentative structures have been proposed.

引用

页码：345 / 353

页数：9

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