PbGaBO4, an orthoborate with a new structure-type

被引：31

作者：

Park, H ^{[1
]}

Barbier, J ^{[1
]}

机构：

[1] McMaster Univ, Dept Chem, Hamilton, ON L8S 4M1, Canada

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷

关键词：

D O I：

10.1107/S1600536801013940

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of a new ternary borate, lead gallium boron tetraoxide, PbGaBO4, has been determined by X-ray diffraction using a single-crystal grown from a PbO flux. The structure consists of infinite [010] chains of edge-sharing GaO6 octahedra bridged by BO3 triangles. The Pb2+ cations and their stereoactive lone pair occupy the apex of PbO4 square pyramids. The structure represents a new structure-type for anhydrous orthoborates. Bond-valence analysis reveals the presence of strain within the octahedral chains.

引用

页码：i82 / I84

页数：3

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