Magnetic Control over Liquid Surface Properties with Responsive Surfactants

被引:184
作者
Brown, Paul [1 ]
Bushmelev, Alexey [2 ]
Butts, Craig P. [1 ]
Cheng, Jing [3 ]
Eastoe, Julian [1 ]
Grillo, Isabelle [4 ]
Heenan, Richard K. [5 ]
Schmidt, Annette M. [2 ]
机构
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
[2] Univ Cologne, Dept Chem, D-50939 Cologne, Germany
[3] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China
[4] Inst Max Von Laue Paul Langevin, F-38042 Grenoble, France
[5] Rutherford Appleton Lab, ISIS STFC, Chilton OX11 0QX, Oxon, England
关键词
ionic liquids; magnetic surfactants; micellization; surface tension; PHASE-BEHAVIOR; WATER; TRANSITION; FIELD; SALTS;
D O I
10.1002/anie.201108010
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Droplet attraction: Surfactants responsive to magnetic fields are reported for the first time. This new class of magnetic ionic liquid surfactants (MILSs; see picture) shows remarkable effects on surface and interfacial tension and allows access to magneto-responsive emulsions and new methods of separation, recovery, catalysis, and potential magnetophoretic applications. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:2414 / 2416
页数:3
相关论文
共 30 条
  • [21] Does magnetic treatment of water change its properties?
    Otsuka, I
    Ozeki, S
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (04) : 1509 - 1512
  • [22] Transient oxygen clathrate-like hydrate and water networks induced by magnetic fields
    Ozeki, Sumio
    Otsuka, Ichiro
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (41) : 20067 - 20072
  • [23] Robb I.D., 1997, Specialist Surfactants
  • [24] INTERNAL MAGNETIC-FIELD EFFECT OF TRANSITION-METAL IONS ON THE PHOTOCHEMICAL-REACTION OF NAPHTHOQUINONE IN MICELLES
    SAKAGUCHI, Y
    HAYASHI, H
    [J]. CHEMICAL PHYSICS, 1992, 162 (01) : 119 - 129
  • [25] MAGNETIC-SUSCEPTIBILITY OF (CH3NH3)2FECL3BR - EXAMPLE OF A CANTED SPIN SYSTEM
    SEMARY, MA
    MOSTAFA, MF
    AHMED, MA
    [J]. SOLID STATE COMMUNICATIONS, 1978, 25 (07) : 443 - 445
  • [26] Rheological behavior in the didodecyldimethylammonium bromide/water system
    Soltero, JFA
    Bautista, F
    Pecina, E
    Puig, JE
    Manero, O
    Proverbio, Z
    Schulz, PC
    [J]. COLLOID AND POLYMER SCIENCE, 2000, 278 (01) : 37 - 47
  • [27] Reversible light-induced critical separation
    Tabor, Rico F.
    Oakley, Richard J.
    Eastoe, Julian
    Faul, Charl F. J.
    Grillo, Isabelle
    Heenan, Richard K.
    [J]. SOFT MATTER, 2009, 5 (01) : 78 - 80
  • [28] Influence of structural variations in 1-alkyl-3-methylimidazolium cation and tetrahalogenoferrate(III) anion on the physical properties of the paramagnetic ionic liquids
    Yoshida, Y
    Saito, GZ
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2006, 16 (13) : 1254 - 1262
  • [29] Conducting and magnetic properties of 1-ethyl-3-methylimidazolium (EMI) salts containing paramagnetic irons:: Liquids [EMI]MIIICl4] (M = Fe and Fe0.5Ga0.5) and solid [EMI]2[FeIICl4]
    Yoshida, Y
    Otsuka, A
    Saito, G
    Natsume, S
    Nishibori, E
    Takata, M
    Sakata, M
    Takahashi, M
    Yoko, T
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2005, 78 (11) : 1921 - 1928
  • [30] CO2-responsive TX-100 emulsion for selective synthesis of 1D or 3D gold
    Zhang, Jianling
    Zhao, Yueju
    Li, Jianshen
    Yang, Guanying
    Han, Buxing
    Wu, Zhonghua
    Li, Zhihong
    [J]. SOFT MATTER, 2010, 6 (24) : 6200 - 6205