Magnetic Control over Liquid Surface Properties with Responsive Surfactants

被引:184
作者
Brown, Paul [1 ]
Bushmelev, Alexey [2 ]
Butts, Craig P. [1 ]
Cheng, Jing [3 ]
Eastoe, Julian [1 ]
Grillo, Isabelle [4 ]
Heenan, Richard K. [5 ]
Schmidt, Annette M. [2 ]
机构
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
[2] Univ Cologne, Dept Chem, D-50939 Cologne, Germany
[3] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China
[4] Inst Max Von Laue Paul Langevin, F-38042 Grenoble, France
[5] Rutherford Appleton Lab, ISIS STFC, Chilton OX11 0QX, Oxon, England
关键词
ionic liquids; magnetic surfactants; micellization; surface tension; PHASE-BEHAVIOR; WATER; TRANSITION; FIELD; SALTS;
D O I
10.1002/anie.201108010
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Droplet attraction: Surfactants responsive to magnetic fields are reported for the first time. This new class of magnetic ionic liquid surfactants (MILSs; see picture) shows remarkable effects on surface and interfacial tension and allows access to magneto-responsive emulsions and new methods of separation, recovery, catalysis, and potential magnetophoretic applications. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:2414 / 2416
页数:3
相关论文
共 30 条
  • [1] ROOM-TEMPERATURE FUSED-SALTS BASED ON COPPER(I) CHLORIDE-1-METHYL-3-ETHYLIMIDAZOLIUM CHLORIDE MIXTURES .1. PHYSICAL-PROPERTIES
    BOLKAN, SA
    YOKE, JT
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1986, 31 (02) : 194 - 197
  • [2] The effects of magnetic fields on water molecular hydrogen bonds
    Cai, Ran
    Yang, Hongwei
    He, Jinsong
    Zhu, Wanpeng
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2009, 938 (1-3) : 15 - 19
  • [3] Structure and magnetic behavior of transition metal based ionic liquids
    Del Sesto, Rico E.
    McCleskey, T. Mark
    Burrell, Anthony K.
    Baker, Gary A.
    Thompson, Joe D.
    Scott, Brian L.
    Wilkes, John S.
    Williams, Peg
    [J]. CHEMICAL COMMUNICATIONS, 2008, (04) : 447 - 449
  • [4] 1-octanol/water partition coefficients of 1-alkyl-3-methylimidazolium chloride
    Domanska, U
    Bogel-Lukasik, E
    Bogel-Lukasik, R
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (13) : 3033 - 3041
  • [5] Self-assembly of light-sensitive sufactants
    Eastoe, J
    Vesperinas, A
    [J]. SOFT MATTER, 2005, 1 (05) : 338 - 347
  • [6] Structural studies of the phase, aggregation and surface behaviour of 1-alkyl-3-methylimidazolium halide plus water mixtures
    Goodchild, Ian
    Collier, Laura
    Millar, Sarah L.
    Prokes, Ivan
    Lord, Jason C. D.
    Butts, Craig P.
    Bowers, James
    Webster, John R. P.
    Heenan, Richard K.
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2007, 307 (02) : 455 - 468
  • [7] Water-N,N-dimethylformamide alkyltrimethylammonium bromide micellar solutions:: Thermodynamic, structural, and kinetic studies
    Graciani, MD
    Muñoz, M
    Rodríguez, A
    Moyá, ML
    [J]. LANGMUIR, 2005, 21 (08) : 3303 - 3310
  • [8] Discovery of a magnetic ionic liquid [bmim]FeCl4
    Hayashi, S
    Hamaguchi, HO
    [J]. CHEMISTRY LETTERS, 2004, 33 (12) : 1590 - 1591
  • [9] Holmberg K, 1998, NOVEL SURFACTANTS
  • [10] Effects of a static magnetic field on water and electrolyte solutions
    Holysz, Lucyna
    Szczes, Aleksandra
    Chibowski, Emil
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2007, 316 (02) : 996 - 1002