Do theories of glass transition that address only the α-relaxation need a new paradigm?

被引:60
作者
Ngai, KL [1 ]
机构
[1] Naval Res Lab, Washington, DC 20375 USA
[2] Max Planck Inst Phys Komplexer Syst, D-01187 Dresden, Germany
关键词
D O I
10.1016/j.jnoncrysol.2005.03.060
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Experimental evidence is presented to show that temperature, volume and/or entropy enter earlier into the Johari-Goldstein (JG) relaxation to assert their influence on the mobility of molecules, long before the primary alpha-relaxation becomes known. Since the JG relaxation is the precursor of alpha-relaxation, a theory of glass transition needs reconsideration if it considers only the alpha-relaxation and it regards the alpha-relaxation as where originate the dependences of molecular mobility on temperature, volume and/or entropy. Actually, many-molecule dynamics transform the precursory JG relaxation to the terminal alpha-relaxation progressively with time. The stronger dependences of the alpha-relaxation time T. on temperature, volume and/or entropy are derived from the weaker dependences of the JG relaxation time tau(JG). A schematic solution of the glass transition problem based on the coupling model and the JG relaxation is proposed.
引用
收藏
页码:2635 / 2642
页数:8
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