Reactions of 2-(5-methyl-2-phenyl-2H-1,2,3-diazaphosphol-4-yl)-4H-1,3,2-benzodioxaphosphinin-4-one with chloral and hexafluoroacetone

被引:5
作者
Mironov, Vladimir F. [1 ,2 ]
Ivkova, Gulnara A. [2 ]
Abdrakhmanova, Liliya M. [1 ]
Mironova, Ekaterina V. [1 ]
Krivolapov, Dmitry B. [1 ]
Konovalova, Irina V. [2 ]
机构
[1] Russian Acad Sci, AE Arbuzov Organ & Phys Chem Inst, Kazan Sci Ctr, Kazan 420088, Russia
[2] Kazan Volga Reg Fed Univ, AM Butlerov Chem Inst, Kazan 420008, Russia
基金
俄罗斯基础研究基金会;
关键词
CHEMISTRY; DIAZAPHOSPHOLES; AZAPHOSPHOLES; DERIVATIVES; ANALOGS;
D O I
10.1016/j.mencom.2011.09.018
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reaction of 2-(5-methyl-2-phenyl-2H-1,2,3-diazaphosphol-4-yl)-4H-1,3,2-benzodioxaphosphinin-4-one with chloral occurs at Pm atom of the 1,3,2-dioxaphosphinine cycle giving mostly 2-chlorocarbonylphenyl 2,2-dichlorovinyl (5-methyl-2-phenyl-2H-1,2,3-diazaphosphol-4-yl)phosphonate, whereas hexafluoroacetone incorporates into the 1,3,2-dioxaphosphorine cycle affording the corresponding 1,3,2-benzodioxaphosphepine.
引用
收藏
页码:282 / 284
页数:3
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