Enhanced CO2 Adsorption Performance on Hierarchical Porous ZSM-5 Zeolite

被引：74
|
作者：
Liu, Qing [1 ]
He, Pingping [1 ,2 ]
Qian, Xingchi [1 ,2 ]
Fei, Zhaoyang [1 ,2 ]
Zhang, Zhuxiu [1 ]
Chen, Xian [1 ]
Tang, Jihai [1 ,3 ]
Cui, Mifen [1 ]
Qiao, Xu [1 ,2 ,3 ]
Shi, Yao [4 ]
机构：
[1] Nanjing Tech Univ, Coll Chem Engn, Nanjing 210009, Jiangsu, Peoples R China
[2] Nanjing Tech Univ, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Jiangsu, Peoples R China
[3] Jiangsu Natl Synerget Innovat Ctr Adv Mat SICAM, Nanjing 210009, Jiangsu, Peoples R China
[4] Zhejiang Univ, Dept Chem & Biol Engn, Minist Educ, Key Lab Biomass Chem Engn, Hangzhou 310027, Zhejiang, Peoples R China
来源：
ENERGY & FUELS | 2017年 / 31卷 / 12期
基金：
中国国家自然科学基金;
关键词：
CARBON-DIOXIDE CAPTURE; SURFACE-AREA; FLUE-GAS; EFFICIENT; POROSITY; PHYSISORPTION; CARBONIZATION; ADSORBENTS; ETHYLENE; METHANOL;
D O I：
10.1021/acs.energyfuels.7b02543
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
Hierarchical porous ZSM-5 (HP-ZSM-5) was constructed using organosilanes as the growth inhibitors for CO2 capture. The properties of adsorbents were characterized by X-ray diffraction, N-2 adsorption/desorption, scanning electron microscopy, temperature-programmed desorption of carbon dioxide, and Al-27 magic angle spinning nuclear magnetic resonance. It was found that HP-ZSM-5 samples synthesized by organosilanes had a significant effect on the microstructure and morphology. CO, adsorption capacity of HP-ZSM-5 was up to 58.26 cm(3) g(-1) at 0 degrees C and 1 bar, significantly higher than that of the ZSM-5 sample. The effective improvement of CO2 adsorption performance mainly originated from the micro-/mesoporous composite structure and complex surface morphology, which can provide low -resistant pathways for CO2 through the porous network. Besides, in situ Fourier transform infrared spectroscopy was carried out to study the adsorption process on adsorbents, and the results indicated that a faster physical adsorption process was achieved as a result of the introduction of mesopores.
引用
收藏
页码：13933 / 13941
页数：9
相关论文
共 50 条
  • [1] Adsorption of CO2 Using Modified ZSM-5 Zeolite in Petrol Engines
    Sethupathi, P. Baskara
    Martin, M. Leenus Jesu
    Chandradass, J.
    PROGRESS IN ADVANCED COMPUTING AND INTELLIGENT ENGINEERING, PROCEEDINGS OF ICACIE 2016, VOLUME 1, 2018, 563 : 433 - 445
  • [2] Rapid CO2 Adsorption over Hierarchical ZSM-5 with Controlled Mesoporosity
    Qian, Xingchi
    Bai, Gaozhi
    He, Pingping
    Fei, Zhaoyang
    Liu, Qing
    Zhang, Zhuxiu
    Chen, Xian
    Tang, Jihai
    Cui, Mifen
    Qiao, Xu
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2018, 57 (49) : 16875 - 16883
  • [3] Adsorption of CO2 onto zeolite ZSM-5: Kinetic, equilibrium and thermodynamic studies
    Jedli, Hedi
    Almoneef, M. M.
    Mbarek, Mohamed
    Jbara, Abdessalem
    Slimi, Khalifa
    FUEL, 2022, 321
  • [4] High CO2 adsorption on improved ZSM-5 zeolite porous structure modified with ethylenediamine and desorption characteristics with microwave
    Amin Kalantarifard
    Amin Ghavaminejad
    Go Su Yang
    Journal of Material Cycles and Waste Management, 2017, 19 : 394 - 405
  • [5] High CO2 adsorption on improved ZSM-5 zeolite porous structure modified with ethylenediamine and desorption characteristics with microwave
    Kalantarifard, Amin
    Ghavaminejad, Amin
    Yang, Go Su
    JOURNAL OF MATERIAL CYCLES AND WASTE MANAGEMENT, 2017, 19 (01) : 394 - 405
  • [6] Synthesis of ZSM-5 Zeolite from Metakaolin and Rice Husk Ash to CO2 Adsorption
    Klunk, Marcos Antonio
    Das, Mohuli
    Dasgupta, Sudipta
    Caetano, Nattan Roberto
    Xavier, Soyane Juceli Siqueira
    de Souza, Debora Machado
    Wander, Paulo Roberto
    Moraes, Carlos Alberto Mendes
    ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY, 2021, 10 (01)
  • [7] Synthesis of ZSM-5 zeolite composite membranes for CO2 separation
    Hyun, SH
    Song, JK
    Kwak, BI
    Kim, JH
    Hong, SA
    JOURNAL OF MATERIALS SCIENCE, 1999, 34 (13) : 3095 - 3103
  • [8] Synthesis of ZSM-5 zeolite composite membranes for CO2 separation
    S. H. Hyun
    J. K. Song
    B. I. Kwak
    J. H. Kim
    S. A. Hong
    Journal of Materials Science, 1999, 34 : 3095 - 3105
  • [9] Adsorption of CO2 on ZSM-5 Zeolite: Analytical Investigation via a Multilayer Statistical Physics Model
    Aouaini, Fatma
    Bouaziz, Nadia
    Alfwzan, Wafa
    Khemiri, Noura
    Elqahtani, Zainab
    Ben Lamine, Abdelmottaleb
    APPLIED SCIENCES-BASEL, 2022, 12 (03):
  • [10] Preparation of high performance ZSM-5 zeolite membranes for CO2/H2 separation
    Mirfendereski, Seyed Mojtaba
    Mazaheri, Tayebeh
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2021, 94 : 240 - 252
12345