Thermo-physical characterization of torrefied fuel pellet from co-pelletization of canola hulls and meal

被引:43
作者
Azargohar, Ramin [1 ]
Soleimani, Majid [1 ]
Nosran, Shivam [1 ]
Bond, Toby [2 ]
Karunakaran, Chithra [2 ]
Dalai, Ajay K. [1 ]
Tabil, Lope G. [1 ]
机构
[1] Univ Saskatchewan, Dept Chem & Biol Engn, Saskatoon, SK, Canada
[2] Canadian Light Source, Saskatoon, SK, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
Canola hull; Canola meal; Pelletization; Torrefaction; Characterization; Computed tomography; MICROWAVE TORREFACTION; PROCESS OPTIMIZATION; TETANUS TOXOIDS; PROTEIN-CONTENT; SEWAGE-SLUDGE; BIOMASS; SAWDUST; PYROLYSIS; LIGNIN; DENSIFICATION;
D O I
10.1016/j.indcrop.2018.11.042
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Agricultural processing residues, as renewable sources of energy, can be converted to value-added products such as fuel pellets with the wide applications in the production of heat and power. In this research, densification/torrefaction of canola meal and canola hull was investigated. A bench-scale extruder was used for densification of canola hull and canola meal. Then, to increase the hydrophobicity and heating value of pellets, they were torrefied. For pelletization of canola meal, an increase in canola meal to water mass ratio resulted in an increase in the mechanical strength of pellets. Canola meal was also used to facilitate pelletization of canola hull. Co-pelletization of canola hull with canola meal was successful for canola hull mass percentage up to 60 wt% in the feedstock. In general, torrefied pellets showed lower moisture adsorption (up to 59%), higher carbon content (in the range of 21-25%), lower oxygen content (35-46%), and higher heating value (up to 22%) compared with their respective precursors. To study the effects of operating conditions and additives, different characterization techniques were used to evaluate the thermal, chemical, mechanical, and physical properties of pellets. Synchrotron-based computed tomography showed that after torrefaction, porosity increased by 10% for pellets from canola meal and increased by 22-30% for pellets prepared by co-pelletization. Addition of alkali lignin to canola meal precursor helped to increase the mechanical strength of torrefied pellet produced from canola meal. The use of binders such as alkali lignin and crude glycerol had no effect on the relaxed density of torrefied pellets and resulted in higher moisture adsorption.
引用
收藏
页码:424 / 435
页数:12
相关论文
共 49 条
[21]   Towards lignin-based functional materials in a sustainable world [J].
Kai, Dan ;
Tan, Mein Jin ;
Chee, Pei Lin ;
Chua, Yun Khim ;
Yap, Yong Liang ;
Loh, Xian Jun .
GREEN CHEMISTRY, 2016, 18 (05) :1175-1200
[22]   SOME FACTORS IN THE INTERPRETATION OF PROTEIN DENATURATION [J].
KAUZMANN, W .
ADVANCES IN PROTEIN CHEMISTRY, 1959, 14 :1-63
[23]   Integrating Torrefaction in the Wood Pellet Industry: A Critical Review [J].
Kumar, Linoj ;
Koukoulas, Alexander A. ;
Mani, Sudhagar ;
Satyavolu, Jagannadh .
ENERGY & FUELS, 2017, 31 (01) :37-54
[24]   Structural transformations of wood and cereal biomass components induced by microwave assisted torrefaction with emphasis on extractable value chemicals obtaining [J].
Lauberts, Maris ;
Lauberte, Liga ;
Arshanitsa, Alexandr ;
Dizhbite, Tatiana ;
Dobele, Galina ;
Bikovens, Oskars ;
Telysheva, Galina .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2018, 134 :1-11
[25]   Pelletization of torrefied sawdust and properties of torrefied pellets [J].
Li, Hui ;
Liu, Xinhua ;
Legros, Robert ;
Bi, Xiaotao T. ;
Lim, C. Jim ;
Sokhansanj, Shahab .
APPLIED ENERGY, 2012, 93 :680-685
[26]   Wet Torrefaction of Bamboo in Hydrochloric Acid Solution by Microwave Heating [J].
Li, Ming-Fei ;
Shen, Yue ;
Sun, Jian-Kui ;
Bian, Jing ;
Chen, Chang-Zhou ;
Sun, Run-Cang .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2015, 3 (09) :2022-2029
[27]   Lignin in storage and renewable energy applications: A review [J].
Luis Espinoza-Acosta, Jose ;
Torres-Chavez, Patricia I. ;
Olmedo-Martinez, Jorge L. ;
Vega-Rios, Alejandro ;
Flores-Gallardo, Sergio ;
Armando Zaragoza-Contreras, E. .
JOURNAL OF ENERGY CHEMISTRY, 2018, 27 (05) :1422-1438
[28]   Structural and chemical modifications of typical South African biomasses during torrefaction [J].
Mafu, Lihle D. ;
Neomagus, Hein W. J. P. ;
Everson, Raymond C. ;
Carrier, Marion ;
Strydom, Christien A. ;
Bunt, John R. .
BIORESOURCE TECHNOLOGY, 2016, 202 :192-197
[29]   Rapid pyrolysis of wood block by microwave heating [J].
Miura, M ;
Kaga, H ;
Sakurai, A ;
Kakuchi, T ;
Takahashi, K .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2004, 71 (01) :187-199
[30]   Effect of extractives and storage on the pelletizing process of sawdust [J].
Nielsen, Niels Peter K. ;
Gardner, Douglas J. ;
Felby, Claus .
FUEL, 2010, 89 (01) :94-98