Palladium-catalyzed sequential reaction via Sonogashira coupling, isomerization, Claisen rearrangement and [4+2] cycloaddition sequence for the rapid synthesis of tricyclo[3.2.1.02,7]oct-3-ene derivatives

被引：17
作者：
Zhu, Shugao [1 ]
Wu, Luling [1 ]
Huang, Xian [1 ,2 ]
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 310028, Zhejiang, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China
来源：
RSC ADVANCES | 2012年 / 2卷 / 01期
基金：
中国国家自然科学基金;
关键词：
ORGANIC-SYNTHESIS; DOMINO REACTIONS; HIGHLY FLUORESCENT; CASCADE REACTIONS; TANDEM REACTIONS; TRANSFORMATIONS; STEREOCHEMISTRY; DICHOTOMIES; METHODOLOGY; STRATEGIES;
D O I：
10.1039/c1ra00452b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An interesting sequential reaction consisting of Sonogashira coupling, propargyl-allenyl isomerization, allenyl-benzyl Claisen rearrangement and [4 + 2] cycloaddition was developed. This reaction provides an efficient synthesis of fused tricyclo [3.2.1.0(2,7)]oct-3-enes.
引用
收藏
页码：132 / 134
页数：3
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