Evidence for Interstitial Carbon in Nitrogenase FeMo Cofactor

被引：710

作者：

Spatzal, Thomas ^{[1
]}

Aksoyoglu, Muege ^{[2
]}

Zhang, Limei ^{[3
]}

Andrade, Susana L. A. ^{[1
,4
]}

Schleicher, Erik ^{[2
]}

Weber, Stefan ^{[2
]}

Rees, Douglas C. ^{[3
]}

Einsle, Oliver ^{[1
,4
]}

机构：

[1] Univ Freiburg, Inst Organ Chem & Biochem, D-79104 Freiburg, Germany

[2] Univ Freiburg, Inst Phys Chem, D-79104 Freiburg, Germany

[3] CALTECH, Howard Hughes Med Inst, Div Chem & Chem Engn, Pasadena, CA 91125 USA

[4] Univ Freiburg, BIOSS Ctr Biol Signalling Studies, D-79104 Freiburg, Germany

来源：

SCIENCE | 2011年 / 334卷 / 6058期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1126/science.1214025

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

引用

页码：940 / 940

页数：1

共 3 条

[1] Nitrogenase MoFe-protein at 1.16 Å resolution:: A central ligand in the FeMo-cofactor [J].

Einsle, O ;

Tezcan, FA ;

Andrade, SLA ;

Schmid, B ;

Yoshida, M ;

Howard, JB ;

Rees, DC .

SCIENCE, 2002, 297 (5587) :1696-1700

[2] Testing if the interstitial atom, X, of the nitrogenase molybdenum-iron cofactor is N or C: ENDOR, ESEEM, and DFT studies of the S=3/2 resting state in multiple environments [J].

Lukoyanov, Dmitriy ;

Pelmenschikov, Vladimir ;

Maeser, Nathan ;

Laryukhin, Mikhail ;

Yang, Tran Chin ;

Noodleman, Louis ;

Dean, Dennis R. ;

Case, David A. ;

Seefeldt, Lance C. ;

Hoffman, Brian M. .

INORGANIC CHEMISTRY, 2007, 46 (26) :11437-11449

[3] Structural basis of biological nitrogen fixation [J].

Rees, DC ;

Tezcan, FA ;

Haynes, CA ;

Walton, MY ;

Andrade, S ;

Einsle, O ;

Howard, JB .

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 2005, 363 (1829) :971-984

← 1 →