High efficient white light emission of rare earth-free MnO-SnO-ZnO-P2O5 glass

被引:25
作者
Masai, Hirokazu [1 ]
Fujiwara, Takumi [2 ]
Matsumoto, Syuji [3 ]
Takahashi, Yoshihiro [2 ]
Iwasaki, Kenichiro [2 ]
Tokuda, Yomei [1 ]
Yoko, Toshinobu [1 ]
机构
[1] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan
[2] Tohoku Univ, Sch Engn, Dept Appl Phys, Sendai, Miyagi 9808579, Japan
[3] Asahi Glass Co Ltd, Res Ctr, Kanagawa Ku, Yokohama, Kanagawa 2118755, Japan
基金
日本科学技术振兴机构;
关键词
Glass; Emission; Sn; Phosphor; Rare earth-free; LUMINESCENCE; PHOSPHORS; BASICITY; SIO2;
D O I
10.2109/jcersj2.119.726
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
White light emission of rare earth (RE)-free Mn-doped SnO-ZnO-P2O5 glass is demonstrated. Glass transition temperature of the obtained glass is below 440 degrees C, which assures the application to sealant of solid state light emitting devices. The RE-free transparent glass shows white light emission with a high value of quantum efficiency (QE) comparable to conventional crystalline phosphor by excitation of deep UV light. The broad emission of RE-free transparent glass can be continuously tuned by both the amount of activator and the composition of the glass without decrease of the QE value. (C)2011 The Ceramic Society of Japan. All rights reserved.
引用
收藏
页码:726 / 730
页数:5
相关论文
共 20 条
[1]  
Akai T., 2005, [No title captured], Patent No. [WO2007017928-A1, 2007017928]
[2]   ALKALINE EARTH ORTHOPHOSPHATE PHOSPHORS [J].
BUTLER, KH .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1953, 100 (05) :250-255
[3]   CALCIUM HALOPHOSPHATE PHOSPHORS .1. ANALYSIS OF EMISSION SPECTRA [J].
BUTLER, KH ;
JEROME, CW .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1950, 97 (09) :265-270
[4]  
Clapp R. H., 1947, J OPT SOC AM, V37, P356
[5]  
Davis T. S., 1971, Journal of Luminescence, V4, P48, DOI 10.1016/0022-2313(71)90008-1
[6]   A THEORY OF SENSITIZED LUMINESCENCE IN SOLIDS [J].
DEXTER, DL .
JOURNAL OF CHEMICAL PHYSICS, 1953, 21 (05) :836-850
[7]   INTERPRETATION OF GLASS CHEMISTRY IN TERMS OF OPTICAL BASICITY CONCEPT [J].
DUFFY, JA ;
INGRAM, MD .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1976, 21 (03) :373-410
[8]   ESTABLISHMENT OF AN OPTICAL SCALE FOR LEWIS BASICITY IN INORGANIC OXYACIDS, MOLTEN SALTS, AND GLASSES [J].
DUFFY, JA ;
INGRAM, MD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (24) :6448-&
[9]   β-band photoluminescence and Sn-E′ center generation from twofold-coordinated Sn Centers in SiO2 glasses produced via sol-gel method [J].
Hayakawa, Tomokatsu ;
Enomoto, Takehiro ;
Nogami, Masayuki .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2006, 45 (6A) :5078-5083
[10]  
Hirayama Hideki, 2011, Oyo Buturi, V80, P319