Synthesis of Functionalized Diaryl Sulfides by Cobalt-Catalyzed Coupling between Arylzinc Pivalates and Diaryl Disulfides

被引：64

作者：

Dong, Zhi-Bing ^{[1
,2
]}

Balkenhohl, Moritz ^{[2
]}

Tan, Eric ^{[3
]}

Knochel, Paul ^{[2
]}

机构：

[1] Wuhan Inst Technol, Sch Chem & Environm Engn, Wuhan 430205, Hubei, Peoples R China

[2] Ludwig Maximilians Univ Munchen, Dept Chem, Butenandtstr 5-13, D-81377 Munich, Germany

[3] Barcelona Inst Sci & Technol, Inst Chem Res Catalonia ICIQ, Av Paisos Catalans 16, Tarragona 43007, Spain

来源：

ORGANIC LETTERS | 2018年 / 20卷 / 23期

基金：

中国国家自然科学基金;

关键词：

ENHANCED AIR; S-ARYLATION; (HETERO)ARYLZINC REAGENTS; ORGANIC SEMICONDUCTORS; NICKEL-CATALYST; CROSS-COUPLINGS; EFFICIENT; PALLADIUM; THIOLS; BOND;

D O I：

10.1021/acs.orglett.8b03319

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient protocol for the cobalt-catalyzed preparation of diaryl sulfides from solid organozinc pivalates and commercially available diaryl disulfides is reported. This cross-coupling proceeds at room temperature and displays a good functional group tolerance, allowing the preparation of a diversity of symmetrical or asymmetrical diaryl sulfides in 60-95% yield.

引用

页码：7581 / 7584

页数：4

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