New heterocyclic precursors for thermal generation of reactive, electron-rich 1,2-diaza-1 3-butadienes

被引：39
作者：
Boeckman, RK [1 ]
Ge, P [1 ]
Reed, JE [1 ]
机构：
[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA
来源：
ORGANIC LETTERS | 2001年 / 3卷 / 23期
关键词：
D O I：
10.1021/ol0165645
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[GRAPHICS] The preparation and thermolysis of new stable heterocyclic precursors of 1,2-diaza-1,3-butadienes is described. The resulting reactive diazadienes are trapped in situ with N-phenyldiazamaleimide. The effect of precursor structure on the temperature at which the diazadienes are generated is discussed.
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页码：3647 / 3650
页数：4
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