Hyperbranched supramolecular polymer constructed from twisted cucurbit[14]uril and porphyrin via host-guest interactions

被引:30
作者
Gao, Zhongzheng [1 ]
Zhang, Jing [1 ]
Sun, Nana [2 ]
Huang, Ying [1 ]
Tao, Zhu [1 ]
Xiao, Xin [1 ]
Jiang, Jianzhuang [2 ]
机构
[1] Guizhou Univ, Key Lab Macrocycl & Supramol Chem Guizhou Prov, Guiyang 550025, Peoples R China
[2] Univ Sci & Technol Beijing, Beijing Key Lab Sci & Applicat Funct Mol & Crysta, Beijing 100083, Peoples R China
来源
ORGANIC CHEMISTRY FRONTIERS | 2016年 / 3卷 / 09期
关键词
METAL-COORDINATION; DRIVEN; COMPLEXATION; CUCURBITURIL; ASSEMBLIES; WATER; PSEUDOPOLYROTAXANES; ARCHITECTURES; ENCAPSULATION; RECOGNITION;
D O I
10.1039/c6qo00310a
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A novel supramolecular polymer Q[14]-TBPyP was successfully constructed from a host twisted cucurbit [14] (Q[14]) molecule and a four-arm 5,10,15,20-tetrakis(N-butyl-4-pyridinium)porphyrin tetrabromide (TBPyP) guest molecule depending on the host-guest interactions and characterized by NMR, ITC, DLS, electronic absorption, and fluorescence spectroscopy, representing the first cucurbit[14]uril-involved host-guest supramolecular polymer.
引用
收藏
页码:1144 / 1148
页数:5
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