Synthesis of graphene-supported Li4Ti5O12 nanosheets for high rate battery application

被引：125
作者：
Tang, Yufeng [1 ,2 ]
Huang, Fuqiang [1 ,2 ,3 ]
Zhao, Wei [1 ,2 ]
Liu, Zhanqiang [1 ,2 ]
Wan, Dongyun [1 ,2 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Ceram, CAS Key Lab Mat Energy Convers, Shanghai 200050, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
[3] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2012年 / 22卷 / 22期
关键词：
LITHIUM-ION BATTERIES; RATE CAPABILITY; ELECTROCHEMICAL PERFORMANCE; SPINEL LI4TI5O12; HYBRID MATERIALS; ANODE MATERIAL; HIGH-CAPACITY; STORAGE; ELECTRODES;
D O I：
10.1039/c2jm30624g
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The composite structure of Li4Ti5O12 (LTO) nanosheets rooted on two-dimensional graphene (GR) was proposed to achieve an enhanced rate performance for high rate lithium ion batteries. Such a nanostructured material of graphene-supported Li4Ti5O12 nanosheets (GR-LTOs) was fabricated by using TiO2 colloid-containing graphene oxide (GO) sheets as precursor in a hydrothermal reaction. TiO2 colloids serve as the seeds to realize the growth of LTO on GR and ensure the tight bonding between GR and LTO to benefit the charge transfer from the two types of sheets. The GR-LTOs sample possesses excellent electrochemical properties with good cycle stability and a high specific capacity of 140 mA h g(-1) at 20 C. It demonstrates that LTO nanosheets, graphene sheets, and their tightly-bonded interfaces provide short ion diffusion distance and good electron conduction in such a composite structure.
引用
收藏
页码：11257 / 11260
页数：4
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