Generation effects on the microstructure and product distribution in ethylene polymerization promoted by dendritic nickel catalysts

被引：48

作者：

Benito, JM ^{[1
]}

de Jesús, E ^{[1
]}

de la Mata, FJ ^{[1
]}

Flores, JC ^{[1
]}

Gómez, R ^{[1
]}

机构：

[1] Univ Alcala De Henares, Dept Quim Inorgan, E-28871 Alcala De Henares, Spain

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 41期

关键词：

D O I：

10.1039/b511379m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbosilane dendrimers Gn-[(ONNMe2)NiBr2] m, containing up to sixteen terminal pyridylimine nickel complexes, have been studied as catalysts for polymerization of ethylene; the microstructure and the oligomer/polymer distribution are significantly affected by the generation of the dendritic precursor.

引用

页码：5217 / 5219

页数：3

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