Surfactant-free microemulsions

被引:106
|
作者
Hou, Wanguo [1 ]
Xu, Jie [2 ]
机构
[1] Shandong Univ, Key Lab Colloid & Interface Chem, Minist Educ, Jinan 250100, Peoples R China
[2] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266042, Peoples R China
基金
中国国家自然科学基金;
关键词
Microemulsion; Surfactant-free microemulsion; Colloid; Phase behavior; Conductivity; WATER-OIL MICROEMULSIONS; PHASE-BEHAVIOR; DETERGENTLESS MICROEMULSIONS; ENZYMATIC-REACTIONS; TERNARY-SYSTEMS; MIXTURES; MEDIA; HYDROLYSIS; CONDUCTIVITY; 2-PROPANOL;
D O I
10.1016/j.cocis.2016.06.013
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Surfactants (or amphiphiles) are generally believed to be a necessary component of microemulsions. However, research has found that in the absence of traditional surfactants, microemulsions can also form in a ternary system of two immiscible fluids and an "amphi-solvent". Such microemulsions are called "surfactant-free microemulsions" (SFMEs). The so-called amphi-solvent is a solvent that is completely or at least partially miscible with each of the two immiscible fluids. The structures and properties of SFMEs are similar to those of traditional surfactant-based microemulsions (SBMEs) to some extent This review focuses on recent advances in SFMEs, including their phase behavior, structures, properties and potential applications. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:67 / 74
页数:8
相关论文
共 50 条
  • [1] Structure and Solubility in Surfactant-Free Microemulsions
    Klossek, Michael L.
    Touraud, Didier
    Zemb, Thomas
    Kunz, Werner
    CHEMPHYSCHEM, 2012, 13 (18) : 4116 - 4119
  • [2] Thermodynamic Explanation of Surfactant-Free Microemulsions
    Ma, Wenchao
    Du, Na
    Hou, Wanguo
    JOURNAL OF PHYSICAL CHEMISTRY B, 2025, 129 (07): : 2115 - 2127
  • [3] Surfactant-free microemulsions with cleavable constituents
    Krickl, Sebastian
    Jurko, Lucija
    Wolos, Karolina
    Touraud, Didier
    Kunz, Werner
    JOURNAL OF MOLECULAR LIQUIDS, 2018, 271 : 112 - 117
  • [4] Salt effects in surfactant-free microemulsions
    Schoettl, Sebastian
    Horinek, Dominik
    JOURNAL OF CHEMICAL PHYSICS, 2018, 148 (22):
  • [5] Surfactant-Free Microemulsions in Fragrance Tinctures
    Boskovic, Perica
    Sokol, Vesna
    Dujmovic, Matea
    Gudelj, Martina
    Prkic, Ante
    JOURNAL OF COSMETIC SCIENCE, 2021, 72 (03) : 292 - 297
  • [6] Solubilization power of surfactant-free microemulsions
    Schoettl, Sebastian
    Matubayasi, Nobuyuki
    Horinek, Dominik
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2020, 22 (39) : 22185 - 22189
  • [7] Toward surfactant-free and water-free microemulsions
    Fischer, Veronika
    Marcus, Julien
    Touraud, Didier
    Diat, Olivier
    Kunz, Werner
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2015, 453 : 186 - 193
  • [8] Influence of additives on the structure of surfactant-free microemulsions
    Marcus, J.
    Touraud, D.
    Prevost, S.
    Diat, O.
    Zemb, T.
    Kunz, W.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (48) : 32528 - 32538
  • [9] Enzymatic reactions in structured surfactant-free microemulsions
    Xenakis, Aristotelis
    Zoumpanioti, Maria
    Stamatis, Haralambos
    CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2016, 22 : 41 - 45
  • [10] Enzyme activity of horseradish peroxidase in surfactant-free microemulsions
    Krickl, Sebastian
    Touraud, Didier
    Bauduin, Pierre
    Zinn, Thomas
    Kunz, Werner
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2018, 516 : 466 - 475