Two different etching techniques were used for the investigation of polarity inversion in the magnesium-doped MOVPE GaN layers deposited on GaN pressure grown substrates. Etching in KOH solution at 100 degrees C and in molten bases at 450 degrees C allowed us to determine precisely the regions of different polarity. Chemically active N-polar GaN areas were removed leaving Ga-polar material intact. The results were confirmed by the TEM examination. (c) 2005 Elsevier B.V. All rights reserved.