Supercapacitor electrode based on three-dimensional graphene-polyaniline hybrid

被引:126
作者
Dong, Xiaochen [2 ]
Wang, Jingxia [2 ]
Wang, Jing [1 ]
Chan-Park, Mary B. [1 ]
Li, Xingao [2 ]
Wang, Lianhui [2 ]
Huang, Wei [2 ]
Chen, Peng [1 ]
机构
[1] Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637457, Singapore
[2] NUPT, KLOEID, IAM, Nanjing 210046, Jiangsu, Peoples R China
基金
新加坡国家研究基金会;
关键词
Three-dimensional graphene; Polyaniline; Supercapacitor electrode; COMPOSITE ELECTRODES; SINGLE-LAYER; CAPACITANCE; CARBON; FILMS; NANOSHEETS;
D O I
10.1016/j.matchemphys.2012.03.066
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Three-dimensional (3D) graphene was synthesized by chemical vapour deposition with nickel foam as a substrate. Based on the 3D graphene foams, free-standing graphene-polyaniline (PANI) hybrids were produced by in-situ polymerization of aniline monomer under acid condition, and characterized by scanning electron microscopy (SEM), Fourier transformation infrared (FTIR), and Raman spectroscopy. Furthermore, we show that supercapacitor electrodes based on the 3D graphene-PANI hybrid exhibit high specific capacitances (346 Fg(-1) at a discharge current density of 4 Ag-1), suggesting that the light and inexpensive 3D graphene foams are a promising candidate for energy storage. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:576 / 580
页数:5
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