EXPERIMENTAL STUDY ON ADSORPTION OF CARBON DIOXIDE ON 13X MOLECULAR SIEVE FOR COOLANT HELIUM PURIFICATION

被引:0
作者
Chang Hua [1 ]
Ma Tao [1 ]
Liu Ling [1 ]
Yin Hua-Qiang [1 ]
He Xue-Dong [1 ]
机构
[1] Tsinghua Univ, Adv Reactor Engn & Safety Key Lab, Minist Educ, Inst Nucl & New Energy Technol, Beijing 100084, Peoples R China
来源
PROCEEDINGS OF THE 21ST INTERNATIONAL CONFERENCE ON NUCLEAR ENGINEERING - 2013, VOL 2 | 2014年
关键词
GAS; REMOVAL; CO2; 5A; WATER;
D O I
暂无
中图分类号
TH [机械、仪表工业];
学科分类号
0802 ;
摘要
The adsorption capability of carbon dioxide on 13X molecular sieve (13XMS) was investigated in a fixed-bed apparatus with two-road gas mixing system by dynamic column breakthrough method with helium as carrier gas at helium purification conditions of high-temperature gas-cooled reactor (HTGR). Experiments were performed at temperatures of 5 degrees C similar to 35 degrees C and low carbon dioxide partial pressure range of 10 similar to 150Pa. By analyzing the breakthrough curve, both equilibrium adsorption capacity and kinetic adsorption capacity at breakthrough point were determined. Based on mass-transfer zone model, the experimental breakthrough curves at different operation conditions were analyzed. The carbon dioxide isotherm on 13XMS was fitted well by Langmuir model and the enthalpy of adsorption of carbon dioxide was estimated.
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页数:8
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