Photo-induced reduction of biomass-derived 5-hydroxymethylfurfural using graphitic carbon nitride supported metal catalysts

被引：55

作者：

Guo, Yuanyuan ^{[1
]}

Chen, Jinzhu ^{[1
]}

机构：

[1] Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China

来源：

RSC ADVANCES | 2016年 / 6卷 / 104期

基金：

中国国家自然科学基金;

关键词：

VISIBLE-LIGHT; HYDROGEN-PRODUCTION; SELECTIVE HYDROGENATION; PHOTOCATALYTIC REDUCTION; MILD CONDITIONS; FACILE APPROACH; ALLOY CATALYST; WATER; G-C3N4; NANOPARTICLES;

D O I：

10.1039/c6ra19153c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photo-catalytic reduction of biomass-derived 5-hydroxymethylfurfural (HMF) into 2,5-dihydroxymethylfuran (DHMF) under visible light irradiation is achieved by using a platinum catalyst supported on graphitic carbon nitride (Pt/g-C3N4). Pt/g-C3N4 acts as a multifunctional and tandem catalyst to successively promote the photo-induced water splitting to form hydrogen and the successive activation of the produced hydrogen for HMF reduction, yielding DHMF yield of 6.5% with TOF of 0.457 h(-1). This research provides a sustainable and green pathway for biomass conversion using solar radiation as a driving force.

引用

页码：101968 / 101973

页数：6

共 61 条

[1] The selective hydrogenation of biomass-derived 5-hydroxymethylfurfural using heterogeneous catalysts [J].

Alamillo, Ricardo ;

Tucker, Mark ;

Chia, Mei ;

Pagan-Torres, Yomaira ;

Dumesic, James .

GREEN CHEMISTRY, 2012, 14 (05) :1413-1419

[2] Polymeric Photocatalysts Based on Graphitic Carbon Nitride [J].

Cao, Shaowen ;

Low, Jingxiang ;

Yu, Jiaguo ;

Jaroniec, Mietek .

ADVANCED MATERIALS, 2015, 27 (13) :2150-2176

[3] g-C3N4-Based Photocatalysts for Hydrogen Generation [J].

Cao, Shaowen ;

Yu, Jiaguo .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2014, 5 (12) :2101-2107

[4] Photodegradation of bisphenol A by highly stable palladium-doped mesoporous graphite carbon nitride (Pd/mpg-C3N4) under simulated solar light irradiation [J].

Chang, Chun ;

Fu, Yu ;

Hu, Meng ;

Wang, Chunying ;

Shan, Guoqiang ;

Zhu, Lingyan .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2013, 142 :553-560

[5] Immobilized Ru Clusters in Nanosized Mesoporous Zirconium Silica for the Aqueous Hydrogenation of Furan Derivatives at Room Temperature [J].

Chen, Jiazhi ;

Lu, Fang ;

Zhang, Junjie ;

Yu, Weiqiang ;

Wang, Feng ;

Gao, Jin ;

Xu, Jie .

CHEMCATCHEM, 2013, 5 (10) :2822-2826

[6] Selective Hydrogenation of Biomass-Based 5-Hydroxymethylfurfural over Catalyst of Palladium Immobilized on Amine-Functionalized Metal-Organic Frameworks [J].

Chen, Jinzhu ;

Liu, Ruliang ;

Guo, Yuanyuan ;

Chen, Limin ;

Gao, Hui .

ACS CATALYSIS, 2015, 5 (02) :722-733

[7] Fe-g-C3N4-Catalyzed Oxidation of Benzene to Phenol Using Hydrogen Peroxide and Visible Light [J].

Chen, Xiufang ;

Zhang, Jinshui ;

Fu, Xianzhi ;

Antonietti, Markus ;

Wang, Xinchen .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (33) :11658-+

[8] Liquid-phase catalytic processing of biomass-derived oxygenated hydrocarbons to fuels and chemicals [J].

Chheda, Juben N. ;

Huber, George W. ;

Dumesic, James A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (38) :7164-7183

[9] A fantastic graphitic carbon nitride (g-C3N4) material: Electronic structure, photocatalytic and photoelectronic properties [J].

Dong, Guoping ;

Zhang, Yuanhao ;

Pan, Qiwen ;

Qiu, Jianrong .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2014, 20 :33-50

[10] Interface Effects in Sunlight-Driven Ag/g-C3N4 Composite Catalysts: Study of the Toluene Photodegradation Quantum Efficiency [J].

Fontelles-Carceller, Olga ;

Munoz-Batista, Mario J. ;

Fernandez-Garcia, Marcos ;

Kubacka, Anna .

ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (04) :2617-2627

← 1 2 3 4 5 6 7 →