Initial degree of detaching bubble adsorption coverage and the kinetics of dynamic adsorption layer formation

被引：26

作者：

Kosior, Dominik ^{[1
]}

Zawala, Jan ^{[1
]}

机构：

[1] Polish Acad Sci, Jerzy Haber Inst Catalysis & Surface Chem, Ul Niezapominajek 8, Krakow, Poland

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2018年 / 20卷 / 04期

关键词：

STAGNANT CAP FORMATION; ASCENDING AIR BUBBLES; SURFACTANT SOLUTIONS; REYNOLDS-NUMBERS; RISING BUBBLES; RISE VELOCITY; MICA SURFACE; STABILITY; MOTION; FILMS;

D O I：

10.1039/c7cp06099h

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The influence of the initial adsorption coverage at the surface of an air bubble (radius 0.74 mm) formed at a capillary orifice on profiles of its rising velocities and shape variations was investigated in n-octanol, n-octyltrimethylammonium bromide (CTAB) and Tween80 solutions of different concentrations. The bubble formation and the degree of adsorption coverage at its surface at the moment of departure were controlled using an elaborated automatic bubble generator (Bubble-on-Demand) coupled with a programmable bubble trap, allowing adsorption time control over the motionless (captured) bubble interface. It was found that the degree of the initial bubble adsorption coverage (whose value was calculated according to the existing adsorption models), has a profound influence on the kinetics of the dynamic adsorption layer (DAL) development.

引用

页码：2403 / 2412

页数：10

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