Base-Catalyzed Direct Transformation of Benzylamines into Benzyl Alcohols

被引：5

作者：

Kanbara, Yutaka ^{[1
]}

Abe, Takafumi ^{[1
]}

Fushimi, Norio ^{[1
]}

Ikeno, Taketo ^{[1
]}

机构：

[1] Mitsubishi Gas Chem Co Inc, Niigata Res Lab, Niigata 9503112, Japan

来源：

SYNLETT | 2012年 / 05期

关键词：

alcohols; amines; catalysis; substitution; solid-phase synthesis; PRESSURE SYNTHESIS; ACID; AMINES; DEAMINATIONS; HETEROCYCLES;

D O I：

10.1055/s-0031-1290595

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Benzylamines were directly transformed into benzyl alcohols in superheated aqueous methanol in the presence of a base catalyst. This process is simple and will provide an alternative industrial route to benzyl alcohols such as xylene glycols.

引用

页码：706 / 710

页数：5

共 33 条

[1] ADKINS H, 1954, ORG REACTIONS, V8, P1
[2] ALIPHATIC DEAMINATIONS IN ORGANIC SYNTHESIS
BAUMGARTEN, RJ
[J]. JOURNAL OF CHEMICAL EDUCATION, 1966, 43 (08) : 398 - +
[3] BOSWELL DE, 1970, TETRAHEDRON LETT, P5265
[4] Brasen W.R., 1963, ORG SYNTH, V4, P582
[5] Bruhne F., 1985, ULLMANNS ENCY IND A, VA4, P6
[6] Bungs J. A., 1961, U. S. Patent, Patent No. 2967854
[7] Clarke H. T., 1932, ORG SYNTH COLL, VI, P455
[8] NEW DEAMINATIONS .9. PYROLYSIS OF N-ALKYL-N,N-DISULFONIMIDES
CURTIS, VA
KNUTSON, FJ
BAUMGARTEN, RJ
[J]. TETRAHEDRON LETTERS, 1981, 22 (03) : 199 - 202
[9] DEKA DC, 1988, J CHEM TECHNOL BIOT, V41, P95
[10] DEKA DC, 1995, INDIAN J CHEM TECHN, V2, P197

← 1 2 3 4 →