Synthesis, Structure and Photoluminescent Property of a New 2D Zn(II) Coordination Polymer Constructed by Biphenyl-3,3′,5,5′-tetracarboxylate

被引：0

作者：

Wang Ji-Jiang ^{[1
]}

Cao Pei-Xiang ^{[1
]}

Gao Lou-Jun ^{[1
]}

Fu Feng ^{[1
]}

Zhang Mei-Li ^{[1
]}

Ren Yi-Xia ^{[1
]}

Hou Xiang-Yang ^{[1
]}

机构：

[1] Yanan Univ, Dept Chem & Chem Engn, Shaanxi Key Lab Chem React Engn, Yanan 716000, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2011年 / 30卷 / 12期

关键词：

biphenyl-3,3 ',5,5 '-tetracarboxylic acid; Zn(II); photoluminescent property; CRYSTAL-STRUCTURES; FRAMEWORK; BEHAVIOR; SERIES; LIGAND;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 2D Zn(II) coordination polymer, [Zn(btc)(0.5)(phen)](n) (1, H(4)btc = biphenyl-3,3',5,5'-tetracarboxylic acid, phen = 1,10-phenanthroline), has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction analysis, elemental analysis and IR spectroscopy. Complex 1 crystallizes in the triclinic system, space group P (1) over bar with a = 7.6878(6), b = 10.3453(8), c = 10.9589(9) angstrom, alpha = 113.3540(10), beta = 90.5460(10), gamma = 90.4280(10)degrees, V = 800.09(11) angstrom(3), Z = 2, D(c) = 1.696 Mg.m(-3), mu = 1.566 mm(-1), F(000) = 414, the final R = 0.0359 and wR = 0.0778 for 2441 observed reflections with I > 2 sigma(I). Complex 1 has a 2D layered network containing dinuclear Zn(II) structural units. The 2D layers are further linked by the phen molecules through pi-pi stacking interactions into a 3D supramolecular framework. The photoluminescent property of 1 was also studied in the solid state at room temperature.

引用

页码：1787 / 1790

页数：4

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