Atom Transfer Radical Reactions as a Tool for Olefin Functionalization - On the Way to Practical Applications

被引：115

作者：

Maria Munoz-Molina, Jose ^{[1
]}

Belderrain, Tomas R. ^{[1
]}

Perez, Pedro J. ^{[1
]}

机构：

[1] Univ Huelva, Lab Catalisis Homogenea, Dept Quim & Ciencia Mat, Unidad Asociada CSIC,Ctr Invest Quim Sostenible C, Huelva 21007, Spain

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2011年 / 21期

关键词：

ATRA reactions; Homogeneous catalysis; Transition metals; Radicals; Olefins; KHARASCH ADDITION-REACTION; SUPPORTED ARYLNICKEL(II) CATALYSTS; CONTAINING IONIC LIQUIDS; REDOX CHAIN ADDITION; CYCLIZATION REACTIONS; ORGANIC POLYHALIDES; ELECTRON-TRANSFER; N-ALLYLTRICHLOROACETAMIDES; ORGANONICKEL(II) COMPLEXES; RUTHENIUM(II) COMPLEXES;

D O I：

10.1002/ejic.201100379

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Transition-metal-catalyzed atom transfer radical reactions of halogenated compounds with olefins constitute a versatile tool in organic synthesis within the area of C-C bond forming transformations. The inter-or intramolecular versions, atom transfer radical addition (ATRA) or cyclization (ATRC), respectively, lead to the atom-economic, useful synthesis of compounds that can be further functionalized. This contribution summarizes the recent developments in this area in terms of catalyst design as well as the applicability of this methodology in sequential, domino, or tandem reactions.

引用

页码：3155 / 3164

页数：10

共 129 条

[51] STEREOELECTRONIC EFFECTS IN THE FORMATION OF 5-MEMBERED AND 6-MEMBERED RINGS - THE ROLE OF BALDWIN RULES [J].