Specific thermal and thermodynamic properties of the tellurites Fe2(TeO3)3, Fe2TeO5 and Fe2Te4O11

被引:5
|
作者
Gospodinov, G. [1 ]
Atanasova, Lubka [1 ]
机构
[1] Univ Prof Assen Zlatarov, Inorgan Chem Technol Dept, Burgas 8010, Bulgaria
关键词
iron tellurites; molar heat capacity;
D O I
10.1007/s10973-007-8460-6
中图分类号
O414.1 [热力学];
学科分类号
摘要
The temperature dependence of the molar heat capacities of the tellurites Fe-2(TeO3)(3), Fe2TeO5 and Fe2Te4O11 were determined. By statistical manipulation of the values obtained, the parameters in the equations for the corresponding compounds showing this dependence were determined using the least-squares method. These equations together with the standard molar entropies were used to determine the thermodynamic functions Delta S-T(0)m(0) , Delta(T)(T), H-m(0) and (Phi(0)(m) + Delta H-T'(0)m(0)/T) for T'=298.15 K.
引用
收藏
页码:655 / 657
页数:3
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