Incorporation of magnetic nanoparticles into lamellar polystyrene-b-poly(n-butyl methacrylate) diblock copolymer films: Influence of the chain end-groups on nanostructuration

被引：11

作者：

Douadi-Masrouki, Siham ^{[1
,2
,3
]}

Frka-Petesic, Bruno ^{[1
,2
,3
]}

Save, Maud ^{[4
,5
]}

Charleux, Bernadette ^{[4
,5
]}

Cabuil, Valerie ^{[1
,2
,3
]}

Sandre, Olivier ^{[1
,2
,3
]}

机构：

[1] Univ Paris 06, UMR Physicochim Electrolytes Colloides & Sci Anal, F-75005 Paris, France

[2] CNRS, UMR PECSA 7195, F-75005 Paris, France

[3] ESPCI ParisTech, UMR PECSA 7195, F-75005 Paris, France

[4] Univ Paris 06, Lab Chim Polymeres, UMR 7610, F-75005 Paris, France

[5] CNRS, UMR LCP 7610, F-75005 Paris, France

来源：

POLYMER | 2010年 / 51卷 / 21期

关键词：

Polymer synthesis; Polymer physical chemistry; Polymer composite materials; TRANSFER RADICAL POLYMERIZATION; CRITICAL ORDERING TRANSITION; THIN-FILMS; BLOCK-COPOLYMERS; PHASE-BEHAVIOR; POLY(BUTYL METHACRYLATE); MICROPHASE SEPARATION; NEUTRON REFLECTIVITY; FEPT NANOPARTICLES; FREE-SURFACE;

D O I：

10.1016/j.polymer.2010.08.043

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In this article, we present new samples of lamellar magnetic nanocomposites based on the self-assembly of a polystyrene-b-poly(n-butyl methacrylate) diblock copolymer synthesized by atom transfer radical polymerization. The polymer films were loaded with magnetic iron oxide nanoparticles covered with polystyrene chains grown by surface initiated-ATRR The nanostructuration of the pure and magnetically loaded copolymer films on silicon was studied by atomic force microscopy, ellipsometry, neutron reflectivity and contact angle measurement. The present study highlights the strong influence of the copolymer extremity driven itself by the choice of the ATRP chemical route on the order of the repetition sequences of the blocks in the multi-lamellar films. In addition, a narrower distribution of the nanoparticles' sizes was examined as a control parameter of the SI-ATRP reaction. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：4673 / 4685

页数：13

共 98 条

[1] Block-copolymer-templated synthesis of iron, iron-cobalt, and cobalt-nickel alloy nanoparticles [J].