Enabling Catalytic Oxidation of Li2O2 at the Liquid-Solid Interface: The Evolution of an Aprotic Li-O2 Battery

被引：121
作者：
Feng, Ningning [1 ]
He, Ping [1 ]
Zhou, Haoshen [1 ,2 ]
机构：
[1] Nanjing Univ, Natl Lab Solid State Microstruct, Coll Engn & Appl Sci, Nanjing 210093, Jiangsu, Peoples R China
[2] Natl Inst Adv Ind Sci & Technol, Energy Technol Res Inst, Tsukuba, Ibaraki 3058568, Japan
来源：
CHEMSUSCHEM | 2015年 / 8卷 / 04期
基金：
中国国家自然科学基金;
关键词：
charging potential; energy storage; homogeneous catalysis; Li-O-2; batteries; redox mediators; BIFUNCTIONAL CATALYST; OXYGEN; PERFORMANCE; COMPOSITE; ELECTRODE;
D O I：
10.1002/cssc.201403338
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We show that by using a suitable soluble redox mediator, the charging overpotential can be reduced and the round-trip efficiency can be improved in an aprotic Li-O-2 battery. Not only do we explore a new redox couple, 10-methyl-10H-phenothiazine, as a soluble catalyst that improves the electrochemical performance, but we also propose possible challenges that need to be overcome for the future improvement of aprotic Li-O-2 batteries.
引用
收藏
页码：600 / 602
页数：3
相关论文
共 30 条
  • [1] [Anonymous], 2014, ANGEW CHEM
  • [2] [Anonymous], ANGEW CHEM
  • [3] TEMPO: A Mobile Catalyst for Rechargeable Li-O2 Batteries
    Bergner, Benjamin J.
    Schuermann, Adrian
    Peppler, Klaus
    Garsuch, Arnd
    Janek, Juergen
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (42) : 15054 - 15064
  • [4] Bruce PG, 2012, NAT MATER, V11, P19, DOI [10.1038/nmat3191, 10.1038/NMAT3191]
  • [5] Chase G. V., 2012, U.S. Patent, Patent No. [2012/0028137, 20120028137]
  • [6] Chen YH, 2013, NAT CHEM, V5, P489, DOI [10.1038/NCHEM.1646, 10.1038/nchem.1646]
  • [7] A Critical Review of Li/Air Batteries
    Christensen, Jake
    Albertus, Paul
    Sanchez-Carrera, Roel S.
    Lohmann, Timm
    Kozinsky, Boris
    Liedtke, Ralf
    Ahmed, Jasim
    Kojic, Aleksandar
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2012, 159 (02) : R1 - R30
  • [8] α-MnO2 nanowires:: A catalyst for the O2 electrode in rechargeable lithium batteries
    Debart, Aurelie
    Paterson, Allan J.
    Bao, Jianli
    Bruce, Peter G.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (24) : 4521 - 4524
  • [9] Core-Shell-Structured CNT@RuO2 Composite as a High-Performance Cathode Catalyst for Rechargeable Li-O2 Batteries
    Jian, Zelang
    Liu, Pan
    Li, Fujun
    He, Ping
    Guo, Xianwei
    Chen, Mingwei
    Zhou, Haoshen
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (02) : 442 - 446
  • [10] Electrochemical Performance of Solid-State Lithium-Air Batteries Using Carbon Nanotube Catalyst in the Air Electrode
    Kitaura, Hirokazu
    Zhou, Haoshen
    [J]. ADVANCED ENERGY MATERIALS, 2012, 2 (07) : 889 - 894
123