Enabling Catalytic Oxidation of Li2O2 at the Liquid-Solid Interface: The Evolution of an Aprotic Li-O2 Battery

被引：122

作者：

Feng, Ningning ^{[1
]}

He, Ping ^{[1
]}

Zhou, Haoshen ^{[1
,2
]}

机构：

[1] Nanjing Univ, Natl Lab Solid State Microstruct, Coll Engn & Appl Sci, Nanjing 210093, Jiangsu, Peoples R China

[2] Natl Inst Adv Ind Sci & Technol, Energy Technol Res Inst, Tsukuba, Ibaraki 3058568, Japan

来源：

CHEMSUSCHEM | 2015年 / 8卷 / 04期

基金：

中国国家自然科学基金;

关键词：

charging potential; energy storage; homogeneous catalysis; Li-O-2; batteries; redox mediators; BIFUNCTIONAL CATALYST; OXYGEN; PERFORMANCE; COMPOSITE; ELECTRODE;

D O I：

10.1002/cssc.201403338

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We show that by using a suitable soluble redox mediator, the charging overpotential can be reduced and the round-trip efficiency can be improved in an aprotic Li-O-2 battery. Not only do we explore a new redox couple, 10-methyl-10H-phenothiazine, as a soluble catalyst that improves the electrochemical performance, but we also propose possible challenges that need to be overcome for the future improvement of aprotic Li-O-2 batteries.

引用

页码：600 / 602

页数：3

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