The role of local anisotropy profiles at grain boundaries on the coercivity of Nd2Fe14B magnets

被引:108
作者
Hrkac, Gino [1 ]
Woodcock, Thomas G. [3 ]
Freeman, Colin L. [1 ]
Goncharov, Alexander [1 ]
Dean, Julian [1 ]
Schrefl, Thomas [1 ,2 ]
Gutfleisch, Oliver [3 ]
机构
[1] Univ Sheffield, Dept Mat Engn, Sheffield S1 3JD, S Yorkshire, England
[2] St Polten Univ Appl Sci, A-3100 St Polten, Austria
[3] IFW Dresden, Inst Metall Mat, D-01171 Dresden, Germany
关键词
ND-RICH PHASE; PERMANENT-MAGNETS; SINTERED MAGNETS; B MAGNETS; SIMULATION; CRYSTAL; GULP; TEM;
D O I
10.1063/1.3519906
中图分类号
O59 [应用物理学];
学科分类号
摘要
We present numerical evidence from atomistic calculations that the coercivity of high-performance NdFeB-sintered-magnets (<20% of the theoretical Stoner-Wolfarth-limit) can be explained by a distorted region of Nd2Fe14B at grain boundaries, which has a reduced local magnetic anisotropy. We show that depending on the boundary composition of fcc-NdO and hcp-Nd2O3, the thickness of this region of reduced anisotropy varies between 0.4 for fcc and 1.6 nm for the hcp phase. For NdO, the distortions are mostly confined in the fcc-NdO-phase but equally distributes in both the hcp-Nd2O3 and Nd2Fe14B. The experimentally measured coercivity of 1.25 T can be understood when taking this distortion and magnetostatic effects into account. (C) 2010 American Institute of Physics. [doi:10.1063/1.3519906]
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页数:3
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