Symmetrical bis-(NHC) palladium(II) complexes: Synthesis, structure, and application in catalysis

被引：26

作者：

Jokic, Nadezda B. ^{[1
]}

Straubinger, Claudia S. ^{[2
]}

Goh, Serena Li Min ^{[1
]}

Herdtweck, Eberhardt ^{[2
]}

Herrmann, Wolfgang A. ^{[2
]}

Kuehn, Fritz E. ^{[1
,2
]}

机构：

[1] Tech Univ Munich, Catalysis Res Ctr, D-85747 Garching, Germany

[2] Tech Univ Munich, Fac Chem, Chair Inorgan Chem, D-85747 Garching, Germany

来源：

INORGANICA CHIMICA ACTA | 2010年 / 363卷 / 15期

关键词：

Catalysis; N-heterocyclic carbenes; Palladium; Suzuki-Miyaura reaction; Polymer-supported catalyst; N-HETEROCYCLIC CARBENES; POLYMER; LIGANDS; REACTIVITY; PHOSPHINE;

D O I：

10.1016/j.ica.2010.06.028

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and characterization of symmetrically substituted bis-N-heterocyclic carbene palladium(II) complexes with a functional group attached to the bridging moiety is described, as well as the immobilization of one of them on polystyrene Wang resin. The resulting complexes were tested both in homogeneous and heterogeneous Suzuki-Miyaura cross-coupling reactions. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：4181 / 4188

页数：8

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