Synthesis, X-ray crystal structure and photophysical properties of tris(dibenzoylmethanido)(1,10-phenanthroline)samarium(III)

被引：45
|
作者：
Stanley, Julie M.
Chan, Christopher K.
Yang, Xiaoping
Jones, Richard A. [1 ]
Holliday, Bradley J.
机构：
[1] Univ Texas Austin, Dept Chem & Biochem, Austin, TX 78712 USA
来源：
POLYHEDRON | 2010年 / 29卷 / 12期
基金：
美国国家科学基金会;
关键词：
Samarium(III) complexes; Dibenzoylmethane; Photoluminescence; Direct triplet excitation; Quantum yield; Radiative lifetime; OPTICAL-PROPERTIES; ENERGY-TRANSFER; COMPLEXES; LUMINESCENT; SM3+; PHOSPHORESCENCE; POLARIZATION; FLUORESCENCE; ENHANCEMENT; LIGANDS;
D O I：
10.1016/j.poly.2010.05.020
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Herein we report for the first time the complete characterization and photophysical properties of tris(dibenzoylmethanido)(1,10-phenanthroline)samarium(III) (Sm(DBM)(3)phen) in the absence of a polymer matrix. The solid state structure of Sm(DBM)(3)phen has been determined by single-crystal X-ray crystallography and shows the geometry of the local coordination environment around the samarium(III) ion to be a slightly distorted square antiprism. The absolute quantum yield and luminescence lifetime were measured as 0.86 +/- 0.40% and 41 +/- 2 mu s, respectively. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2511 / 2515
页数：5
相关论文
共 50 条
  • [1] Synthesis, Crystal Structure and Magnetic Properties of a Nd(III) Coordination Polymer Constructed by 3-Carboxyphenoxyacetate and 1,10-Phenanthroline
    Gu Jin-Zhong
    Shao Yong-Liang
    Zhu Kong-Yang
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2013, 29 (07) : 1480 - 1484
  • [2] Synthesis and Properties of Three Tris(1,10-phenanthroline) ruthenium (Ⅱ) Derivatives
    Fa Ming TIAN
    Peng WANG
    Guo Yi ZHU (Laboratory of Electroanalytical Chemistry
    Chinese Chemical Letters, 1999, (10) : 881 - 884
  • [3] Bis(μ2-1-Carboxybenzene-2-Carboxylato)diaqua(monohydrogen Phthalato)-(1,10-Phenanthroline)samarium(III): Hydrothermal Synthesis and Crystal Structure
    Yu, L. C.
    Lai, L.
    Liu, S. L.
    Xia, Y.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2009, 35 (11) : 864 - 867
  • [4] Electronic structure and optical properties of Eu(III) tris-β-diketonate adducts with 1,10-phenanthroline
    Shurygin, A. V.
    Korochentsev, V. V.
    Cherednichenko, A. I.
    Mirochnik, A. G.
    Kalinovskaya, I. V.
    Vovna, V. I.
    JOURNAL OF MOLECULAR STRUCTURE, 2018, 1155 : 133 - 142
  • [5] SYNTHESIS, STRUCTURE, AND PHOTOLUMINESCENT PROPERTIES OF LANTHANIDE(III) COMPLEXES WITH A LIGAND BASED ON 1,10-PHENANTHROLINE AND BORNEOL
    Bryleva, Yu. A.
    Piryazev, D. A.
    Glinskaya, L. A.
    Agafontsev, A. M.
    Rakhmanova, M. I.
    Tkachev, A. V.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2020, 61 (11) : 1810 - 1822
  • [6] SYNTHESIS, STRUCTURE, AND PHOTOLUMINESCENT PROPERTIES OF LANTHANIDE(III) COMPLEXES WITH A LIGAND BASED ON 1,10-PHENANTHROLINE AND BORNEOL
    Yu. A. Bryleva
    D. A. Piryazev
    L. A. Glinskaya
    A. M. Agafontsev
    M. I. Rakhmanova
    A. V. Tkachev
    Journal of Structural Chemistry, 2020, 61 : 1810 - 1822
  • [7] Synthesis and properties of three tris(1,10-phenanthroline) ruthenium (II) derivatives
    Tian, FM
    Wang, P
    Zhu, GY
    CHINESE CHEMICAL LETTERS, 1999, 10 (10) : 881 - 884
  • [8] Photophysical Properties of Fluorescent 2-(Phenylamino)-1,10-phenanthroline Derivatives
    Teixeira, Rodolfo I.
    da Silva, Ramon B.
    Gaspar, Caio S.
    de Lucas, Nanci C.
    Garden, Simon J.
    PHOTOCHEMISTRY AND PHOTOBIOLOGY, 2021, 97 (01) : 47 - 60
  • [9] Design, synthesis, and photophysical properties of Re(I) tricarbonyl 1,10-phenanthroline complexes
    Komreddy, Venugopal
    Ensz, Kevin
    Huy Nguyen
    Rillema, D. Paul
    Moore, Curtis E.
    JOURNAL OF MOLECULAR STRUCTURE, 2021, 1223
  • [10] Synthesis, Crystal Structure and Fluorescence Spectrum of Terbium(III) Complex with Homoveratric Acid and 1,10-Phenanthroline
    Wang Yan-Fang
    Liu Jian-Feng
    Zhao Guo-Liang
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2010, 26 (02) : 328 - 332
12345