Synthesis and characterization of bulky salen-type complexes of Co, Cu, Fe, Mn and Ni with amphiphilic solubility properties

被引:67
作者
Haikarainen, A
Sipilä, J
Pietikäinen, P
Pajunen, A
Mutikainen, I
机构
[1] Univ Helsinki, Dept Chem, Organ Chem Lab, FIN-00014 Helsinki, Finland
[2] Univ Helsinki, Dept Chem, Inorgan Chem Lab, FIN-00014 Helsinki, Finland
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 07期
关键词
D O I
10.1039/b008167l
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Several new bulky salen-type Schiff base ligands and their complexes with first-row transition metals Co, Cu, Fe, Mn and Ni have been synthesized and characterized. The ligands contain tert-butyl and methyl(triphenylphosphonium chloride) substituents in aromatic rings providing flexible solubility properties. Crystal structures of some of the complexes were determined.
引用
收藏
页码:991 / 995
页数:5
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