Synthesis and transformations of metallacycles - 29. Direct alumination of olefins, conjugated dienes, and acetylenes with alkylhaloalanes catalyzed by Zr and Ti complexes

被引：3

作者：

Dzhemilev, UM ^{[1
]}

Ibragimov, AG

Yakovleva, LG

Khafizova, LO

Borisova, AL

Yakupova, LR

机构：

[1] Bashkortostan Republ Acad Sci, Inst Petrochem & Catal, Ufa 450075, Russia

[2] Russian Acad Sci, Ufa Res Ctr, Ufa 450075, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2003年 / 52卷 / 07期

基金：

俄罗斯基础研究基金会;

关键词：

organoaluminum compounds; titanium- and zirconium-containing catalysts; metallacycles; olefins; dienes; acetylenes; 60]fullerene; alumination;

D O I：

10.1023/A:1025697110484

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytic methods were developed for the synthesis of acyclic 1,2- and 1,4-dialuminum Compounds by the reactions of olefins, dienes, or acetylenes with R2AlCl (R = Et, Et2N, (cyclo-C6H11)(2)N, (BuO)-O-n, or n-C6H13O) in the presence of Ti- or Zr-containing complex catalysts and magnesium metal as an acceptor of chloride ions.

引用

页码：1573 / 1583

页数：11

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