Thermal and photoluminescence properties of hydrated YPO4:Eu3+ nanowires

被引：64
作者：
Di, Weihua
Zhao, Xiaoxia
Lu, Shaozhe
Wang, Xiaojun
Zhao, Haifeng
机构：
[1] Chinese Acad Sci, Changchun Inst Opt Fine Mech & Phys, Key Lab Excited State Phys, Changchun 130033, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2007年 / 180卷 / 09期
基金：
中国国家自然科学基金;
关键词：
rare earth; yttrium orthophosphate; hydrate; luminescence; thermal effect;
D O I：
10.1016/j.jssc.2007.06.025
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In this work, we used the solution precipitation route to synthesize Eu3+-doped YPO4 center dot nH(2)O nanowires. The structure, morphology, composition, thermal behavior, and photoluminescence of as-synthesized product were characterized by X-ray diffraction (XRD), thermogravimetric and differential thermal analysis (TG/DTA), energy-dispersive X-ray spectroscopy (EDS), Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscopic (FE-SEM) and photoluminescence (PL) spectra. The dependence of the structure, morphology, composition and luminescent properties on the thermal treatment was investigated. The results indicate that the aqueous synthesis has a better control on the structure, morphology, composition of the products, and that the heat treatment induces the transitions of the structure, composition, and luminescent properties. (c) 2007 Elsevier Inc. All rights reserved.
引用
收藏
页码：2478 / 2484
页数：7
相关论文
共 32 条
[1]   Epitaxial synthesis of uniform cerium phosphate one-dimensional nanocable heterostructures with improved luminescence [J].
Bu, WB ;
Hua, Z ;
Chen, HR ;
Shi, JL .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (30) :14461-14464
[2]   Surfactant-assisted synthesis of Tb(III)-doped cerium phosphate single-crystalline nanorods with enhanced green emission [J].
Bu, WB ;
Chen, HR ;
Hua, ZL ;
Liu, ZC ;
Huang, WM ;
Zhang, LX ;
Shi, JL .
APPLIED PHYSICS LETTERS, 2004, 85 (19) :4307-4309
[3]   Colloidal synthesis of luminescent rhabdophane LaPO4:Ln3+•xH2O (Ln = Ce, Tb, Eu; x ≈ 0.7) nanocrystals [J].
Buissette, V ;
Moreau, M ;
Gacoin, T ;
Boilot, JP ;
Chane-Ching, JY ;
Le Mercier, T .
CHEMISTRY OF MATERIALS, 2004, 16 (19) :3767-3773
[4]   Visible upconversion of Er3+ doped nanocrystalline and bulk Lu2O3 [J].
Capobianco, JA ;
Vetrone, F ;
Boyer, JC ;
Speghini, A ;
Bettinelli, M .
OPTICAL MATERIALS, 2002, 19 (02) :259-268
[5]   Experimental demonstration of the relationship between the OH- content and photoluminescence in Tb-doped YPO4•2H2O -: art. no. 011907 [J].
Di, WH ;
Wang, XJ ;
Chen, BJ ;
Lu, SZ ;
Ren, XG .
APPLIED PHYSICS LETTERS, 2006, 88 (01)
[6]   Effect of OH- on the luminescent efficiency and lifetime of Tb3+ doped yttrium orthophosphate synthesized by solution precipitation [J].
Di, WH ;
Wang, XJ ;
Chen, BJ ;
Lu, SZ ;
Zhao, XX .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (27) :13154-13158
[7]   Indium phosphide nanowires as building blocks for nanoscale electronic and optoelectronic devices [J].
Duan, XF ;
Huang, Y ;
Cui, Y ;
Wang, JF ;
Lieber, CM .
NATURE, 2001, 409 (6816) :66-69
[8]   Selective synthesis of hexagonal and tetragonal dysprosium orthophosphate nanorods by a hydrothermal method [J].
Fang, YP ;
Xu, AW ;
Qin, AM ;
Yu, RJ .
CRYSTAL GROWTH & DESIGN, 2005, 5 (03) :1221-1225
[9]   Systematic synthesis and characterization of single-crystal lanthanide orthophosphate nanowires [J].
Fang, YP ;
Xu, AW ;
Song, RQ ;
Zhang, HX ;
You, LP ;
Yu, JC ;
Liu, HQ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (51) :16025-16034
[10]  
Hebbink GA, 2002, ADV MATER, V14, P1147, DOI 10.1002/1521-4095(20020816)14:16<1147::AID-ADMA1147>3.0.CO
1234