Flash vacuum pyrolysis of argentilactone

被引：0
|
作者：
McNab, Hamish
Priestap, Horacio A.
Tyas, Richard G.
机构：
[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
[2] Univ Buenos Aires, Fac Farm & Bioquim, RA-1113 Buenos Aires, DF, Argentina
来源：
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS | 2007年 / 80卷 / 01期
关键词：
flash vacuum pyrolysis; dihydropyranones; retro-diels-alder;
D O I：
10.1016/j.jaap.2007.02.001
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The thermal behaviour of argentilactone 1 has been studied by the use of flash vacuum pyrolysis (FVP) techniques. The E- and Z-isomers of 2-octenal 7 were found to be the major non-gaseous products of the thermal ring-opening of argentilactone at 650-850 degrees C; no undecatrienes 2-6 could be identified in the pyrolysate mixtures. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：182 / 186
页数：5
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