Adjusting the Energy-Storage Characteristics of 0.95NaNbO3-0.05Bi(Mg0.5Sn0.5)O3 Ceramics by Doping Linear Perovskite Materials

被引:51
作者
Chen, Hongyun [1 ]
Wang, Xiang [1 ]
Dong, Xiaoyan [1 ]
Pan, Yue [1 ]
Wang, Jiaming [1 ]
Deng, Lian [1 ]
Dong, Qingpeng [1 ]
Zhang, Hailin [1 ]
Zhou, Huanfu [1 ]
Chen, Xiuli [1 ]
机构
[1] Guilin Univ Technol, Key Lab Nonferrous Mat & New Proc Technol, Collaborat Innovat Ctr Explorat Hidden Nonferrous, Minist Educ,Sch Mat Sci & Engn, Guilin 541004, Peoples R China
关键词
unequal substitution; residual polarization; breakdown electric field strength; fast charge-discharge speed; energy-storage properties; RELAXOR FERROELECTRIC CERAMICS; LEAD-FREE CERAMICS; FREE NANBO3-BASED CERAMICS; DECENT FATIGUE ENDURANCE; FREQUENCY STABILITY; DENSITY; PERFORMANCE; EFFICIENCY; PHASE; TEMPERATURE;
D O I
10.1021/acsami.2c01043
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Passive electronic components are an indispensable part of integrated circuits, which are key to the miniaturization and integration of electronic components. As an important branch of passive devices, the relatively low energy-storage capacity of ceramic capacitors limits their miniaturization. To solve this problem, this study adopts the strategy of doping linear materials, specifically CT, into 0.95NaNbO(3)-0.05Bi(Mg0.5Sn0.5)O-3 (0.95NN-0.05BMS) ceramics to increase the disorder of the system through the nonequivalent substitution of A and B sites to achieve the sintering temperature and the residual polarization. Meanwhile, the breakdown electric field strength (E-b) is improved by adjusting the activation energy of the material and the relative density of the sample. Thus, an ultrahigh W-rec of 6.35 J/cm(3) and a eta of 80% are obtained at an E-b of 646 kV/cm. Additionally, through the analysis of the dielectric temperature spectrum, it is found that the 0.88(0.95NN-0.05BMS)-0.12CT sample can satisfy the technical standards of general ceramic Z5U and patch ceramic X6R. The performance of the ceramics also remains stable within a temperature range of 20-200 degrees C, a frequency range of 1-100 Hz, and 10(4) cycles. The charge and discharge tests of the ceramics show that the t(0.9) of the sample floats between 1.02 and 1.04 mu s, which illustrates its potential application in the field of pulsed power components.
引用
收藏
页码:25609 / 25619
页数:11
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