Pd-catalyzed intramolecular aminofluorination of allylic sulfamides

被引：8
|
作者：
Cheng, Jiashun [1 ]
Chen, Pinhong [1 ]
Liu, Guosheng [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
CHINESE JOURNAL OF CATALYSIS | 2015年 / 36卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Palladium-catalyzed; Aminofluorination; Alkene; Fluorinated 1,3-diamine; 6-Endo cyclization; UNACTIVATED ALKENES; EFFICIENT SYNTHESIS; OXIDATIVE AMINOFLUORINATION; STYRENES; HETEROCYCLES; SELECTFLUOR; DERIVATIVES; CYCLIZATION; ALKYNES;
D O I：
10.1016/S1872-2067(14)60164-9
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A facile Pd-catalyzed intramolecular aminofluorination reaction of allylic sulfamides was developed that can be used to prepare fluorinated 1,3-diamine derivatives. Acetic acid was essential for regulation to give the major 6-endo cyclization products. (C) 2015, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：40 / 47
页数：8
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