Light-driven water oxidation with a molecular tetra-cobalt(III) cubane cluster

被引：91

作者：

La Ganga, Giuseppina ^{[1
,2
]}

Puntoriero, Fausto ^{[1
,2
]}

Campagna, Sebastiano ^{[1
,2
]}

Bazzan, Irene ^{[3
,4
]}

Berardi, Serena ^{[3
,4
]}

Bonchio, Marcella ^{[3
,4
]}

Sartorel, Andrea ^{[3
,4
]}

Natali, Mirco ^{[5
,6
]}

Scandola, Franco ^{[5
,6
]}

机构：

[1] Univ Messina, Dipartimento Chim Inorgan Chim Analit & Chim Fis, I-98166 Messina, Italy

[2] Ctr Interuniv Convers Chim Energia Solare, Sez Messina, I-98166 Messina, Italy

[3] Univ Padua, Dept Chem Sci, I-35131 Padua, Italy

[4] ITM CNR, I-35131 Padua, Italy

[5] Sez Ferrara, Dipartimento Chim, I-49100 Ferrara, Italy

[6] Sez Ferrara, Ctr Interuniv Convers Chim Energia Solare, I-49100 Ferrara, Italy

来源：

FARADAY DISCUSSIONS | 2012年 / 155卷

关键词：

OXYGEN-EVOLVING CATALYST; VISIBLE-LIGHT; CRYSTAL-STRUCTURE; ELECTRON-TRANSFER; PHOTOSYSTEM-II; COMPLEXES; EVOLUTION; METAL; CHEMISTRY; ENERGY;

D O I：

10.1039/c1fd00093d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photoinduced water oxidation to molecular oxygen takes place in systems made of [Ru(bpy)(3)](2+) (bpy 2,2'-bipyridine) as the photosensitizer, [Co4O4(O2CMe)(4)(py)(4)] (py pyridine) as the molecular catalyst and Na2S2O8 as the sacrificial electron acceptor. The photochemical quantum yield of the process reaches the outstanding value of 30% and depends on pH and catalyst concentration. Transient absorption spectroscopy experiments aimed to clarify the first events of the photocatalytic process are also reported.

引用

页码：177 / 190

页数：14

共 50 条

[1] Polyoxometalate-Based Cobalt-Phosphate Molecular Catalysts for Visible Light-Driven Water Oxidation
Han, Xin-Bao
Zhang, Zhi-Ming
Zhang, Teng
Li, Yang-Guang
Lin, Wenbin
You, Wansheng
Su, Zhong-Min
Wang, En-Bo
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (14) : 5359 - 5366
[2] Cobalt salophen complexes for light-driven water oxidation
Asraf, Md Ali
Younus, Hussein A.
Ezugwu, Chizoba I.
Mehta, Akshay
Verpoort, Francis
CATALYSIS SCIENCE & TECHNOLOGY, 2016, 6 (12) : 4271 - 4282
[3] Immobilising a cobalt cubane catalyst on a dyesensitised TiO2 photoanode via electrochemical polymerisation for light-driven water oxidation
Li, Jialing
Jiang, Yi
Zhang, Qian
Zhao, Xiaochen
Li, Na
Tong, Haili
Yang, Xiaoxuan
Xia, Lixin
RSC ADVANCES, 2017, 7 (07): : 4102 - 4107
[4] Efficient light-driven water oxidation catalyzed by a mononuclear cobalt(III) complex
Zhao, Yukun
Lin, Junqi
Liu, Yongdong
Ma, Baochun
Ding, Yong
Chen, Mindong
CHEMICAL COMMUNICATIONS, 2015, 51 (97) : 17309 - 17312
[5] Atomic structure of cobalt-oxide nanoparticles active in light-driven catalysis of water oxidation
Risch, Marcel
Shevchenko, Denys
Anderlund, Magnus F.
Styring, Stenbjorn
Heidkamp, Jonathan
Lange, Kathrin M.
Thapper, Anders
Zaharieva, Ivelina
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (10) : 8878 - 8888
[6] A Molecular Light-Driven Water Oxidation Catalyst
Kaveevivitchai, Nattawut
Chitta, Raghu
Zong, Ruifa
El Ojaimi, Maya
Thummel, Randolph P.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (26) : 10721 - 10724
[7] Light-driven water oxidation for solar fuels
Young, Karin J.
Martini, Lauren A.
Milot, Rebecca L.
Snoeberger, Robert C., III
Batista, Victor S.
Schmuttenmaer, Charles A.
Crabtree, Robert H.
Brudvig, Gary W.
COORDINATION CHEMISTRY REVIEWS, 2012, 256 (21-22) : 2503 - 2520
[8] Catalytic oxidation of p-xylene in water by cobalt(III) cubane cluster
Chakrabarty, Rajesh
Kalita, Dipika
Das, Birinchi K.
POLYHEDRON, 2007, 26 (06) : 1239 - 1244
[9] Green oxidation of alcohols with hydrogen peroxide catalyzed by a tetra-cobalt polyoxometalate in water
Farsani, Mostafa Riahi
Assady, Elham
Jalilian, Fariba
Yadollahi, Bahram
Rudbari, Hadi Amiri
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2015, 12 (07) : 1207 - 1212
[10] Visible light-driven water oxidation-from molecular catalysts to photoelectrochemical cells
Duan, Lele
Tong, Lianpeng
Xu, Yunhua
Sun, Licheng
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (09) : 3296 - 3313

← 1 2 3 4 5 →