Comparative study for fluidized bed pyrolysis of textile dyeing sludge and municipal sewage sludge

被引:67
作者
Liu, Yang [1 ,2 ,3 ]
Ran, Chunmei [1 ,2 ]
Siyal, Asif Ali [1 ,2 ]
Song, Yongmeng [1 ,2 ]
Jiang, Zhihui [1 ,2 ]
Dai, Jianjun [1 ,2 ]
Chtaeva, Polina [1 ,2 ]
Fu, Jie [1 ,2 ]
Ao, Wenya [1 ,2 ,3 ]
Deng, Zeyu [1 ,2 ]
Zhang, Tianhao [1 ,2 ]
机构
[1] Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China
[2] Beijing Univ Chem Technol, Coll Chem Engn, Beijing 100029, Peoples R China
[3] Beijing Univ Chem Technol, Beijing Adv Innovat Ctr Soft Matter Sci & Engn, Beijing 100029, Peoples R China
关键词
Fluidized bed; Pyrolysis; Textile dyeing sludge; Municipal sewage sludge; Comparative study; SULFUR TRANSFORMATION; BIO-OIL; BIOCHAR; MICROWAVE; BIOMASS; CARBONIZATION; INCINERATION; GASIFICATION; TEMPERATURE; PERFORMANCE;
D O I
10.1016/j.jhazmat.2020.122619
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A comparative research was performed to evaluate the products yields and chars properties for pyrolysis of textile dyeing sludge (TDS) and municipal sewage sludge (MSS). The high fixed carbon (19.36 wt%) and low volatile (23.66 wt%) contents of TDS resulted in higher char yields and lower condensate yields. TDS char (TC) had a higher sulfur (S) retention efficiency than MSS char (MC) and CaO exhibited a great S retention effect in MC. More alkali and alkaline earth metals (e.g. Na, K, Mg and Ca) in MSS contributed to enhanced catalytic pyrolysis. In comparison to non-catalytic pyrolysis, chars from catalytic pyrolysis had lower iodine number and higher methylene blue (MB) adsorption value. MB adsorption values of MC (212.28-414.20 mg/g) were much higher than those of TC (84.32-156.07 mg/g). In contrast, heavy metals risk degrees of MC (4.20-7.56) were lower than those of TC (7.55-12.87), and heavy metals in TC and MC showed slight risks to environment.
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页数:14
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