Lithium lanthanum titanate perovskite ionic conductor: Influence of europium doping on structural and optical properties

被引:11
作者
Fernandes, Silvia Leticia [1 ]
Gasparotto, Gisele [1 ]
Teixeira, Guilhermina Ferreira [1 ]
Cebim, Marco Aurelio [1 ]
Longo, Elson [2 ]
Zaghete, Maria Aparecida [1 ]
机构
[1] Univ Estadual Paulista, UNESP, Inst Chem, Araraquara, SP, Brazil
[2] Univ Fed Sao Carlos, UFSCAR, Dept Chem, Sao Carlos, SP, Brazil
基金
巴西圣保罗研究基金会;
关键词
Perovskite; Photoluminescence; Lithium lanthanum titanate; Lithium battery; EU3+; PHOTOLUMINESCENCE; LA2/3-XLI3XTIO3; BATTERIES; PHASE; FILMS; SITE;
D O I
10.1016/j.ceramint.2018.08.221
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The present study reports the insertion of europium ions into the network of lithium lanthanum titanate, La0.5Li0.5TiO3, powders. The materials were prepared efficiently via the Pechini method and were characterized using thermogravimetric analyses, X-ray diffraction, high-resolution electron microscopy and photoluminescence spectroscopy. The results obtained demonstrate the high structural disorder of La0.5Li0.5TiO3 (LLTO) as well as the different environments noticed by Eu3+ ions in the La0.5Li0.5TiO3 host lattice. Our results are essentially important once they unfold a better understanding of the complex nature of La0.5Li0.5TiO3 compounds structure.
引用
收藏
页码:21578 / 21584
页数:7
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