Preparation and mechanical properties of unidirectional boron nitride fibre reinforced silica matrix composites

被引:32
作者
Li, Duan [1 ]
Zhang, Chang-Rui [1 ]
Li, Bin [1 ]
Cao, Feng [1 ]
Wang, Si-Qing [1 ]
机构
[1] Natl Univ Def Technol, Coll Aerosp & Mat Engn, State Key Lab Adv Ceram Fibres & Composites, Changsha 410073, Hunan, Peoples R China
基金
中国国家自然科学基金;
关键词
A. Composites: ceramic matrix; E; Mechanical; G. X-ray analysis; PRECURSOR INFILTRATION; PERHYDROPOLYSILAZANE; FABRICATION; RESISTANCE; KINETICS;
D O I
10.1016/j.matdes.2011.08.040
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The unidirectional BNf/SiO2 composites were prepared via sol-gel method, and the structure, composition and mechanical properties were studied. The results show that the composites consist of BN fibres and alpha-cristobalite matrix probably as well as the interface phases of Si3N4 and B2O3. The composites have a density of 1.70 g cm(-3) and an open porosity of 20.8%. The average flexural strength, elastic modulus and fracture toughness at room temperature are 51.2 MPa, 23.2 GPa and 1.46 MPa M-1/2, respectively. The composites show a very plane fracture surface with practically no pulled-out fibres. The mechanical properties of BNf/SiO2 composites at 300-1000 degrees C are desirable, with the maximum flexural strength and residual ratio being 80.2 MPa and 156.8% at 500 degrees C, respectively, while it is a sharply reduced trend as for SiO2f/SiO2 composites. The high thermal stability of BN fibres and self-healing properties caused by the fused SiO2 and B2O3 enable the composites fine high-temperature mechanical properties. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:401 / 405
页数:5
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