Self-assembled Cages and Capsules Using Cyclotriveratrylene-type Scaffolds

被引：41
|
作者：
Hardie, Michaele J. [1 ]
机构：
[1] Univ Leeds, Sch Chem, Woodhouse Lane, Leeds LS2 9JT, W Yorkshire, England
来源：
CHEMISTRY LETTERS | 2016年 / 45卷 / 12期
基金：
英国工程与自然科学研究理事会;
关键词：
Metallocage; Cryptophane; Host-guest complex; COORDINATION POLYMERS; SUPRAMOLECULAR CHEMISTRY; SPONTANEOUS RESOLUTION; METAL COORDINATION; STELLA OCTANGULA; SOLID-STATE; LIGANDS; GUEST; ENCAPSULATION; CRYPTOPHANES;
D O I：
10.1246/cl.160780
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Pyramidal molecular hosts related to cyclotriveratrylene (CTV) form self-assembled cages including organic cages, hydrogen-bonded cages, and metallocages. The latter include M3L2, M4L4, M6L8, and M12L8 assemblies, including topologically complicated structures. Metallocages may show ligand exchange and/or homochiral sorting of the C-3-symmetric CTV-analog ligands. Cages also occur within coordination networks.
引用
收藏
页码：1336 / 1346
页数：11
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