{2,4-Dichloro-6-[2-(dimethylamino)ethyliminomethyl]phenolato}thiocyanatocopper(II)

被引:5
作者
You, ZL [1 ]
机构
[1] Liaoning Normal Univ, Dept Chem & Chem Engn, Dalian 116029, Peoples R China
关键词
D O I
10.1107/S1600536805031107
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [Cu(C11H12Cl2N2O)(NCS)], is a mononuclear Schiff base copper(II) complex. The Cu-II atom is coordinated by one O and two N atoms of the Schiff base ligand, and by one N atom of the thiocyanate ligand, forming a square-planar coordination. The molecule possesses crystallographic mirror symmetry, with one disordered CH2 group.
引用
收藏
页码:M2226 / M2227
页数:2
相关论文
共 15 条
[1]   Synthesis and characterization of new chiral Schiff base complexes with diiminobinaphthyl or diiminocyclohexyl moieties as potential enantioselective epoxidation catalysts [J].
Bernardo, K ;
Leppard, S ;
Robert, A ;
Commenges, G ;
Dahan, F ;
Meunier, B .
INORGANIC CHEMISTRY, 1996, 35 (02) :387-396
[2]  
Bruker, 1998, SMART VERS 5 628 SAI
[3]   Helical-chain copper(II) complexes and a cyclic tetranuclear copper(II) complex with single syn-anti carboxylate bridges and ferromagnetic exchange interactions [J].
Colacio, E ;
Ghazi, M ;
Kivekäs, R ;
Moreno, JM .
INORGANIC CHEMISTRY, 2000, 39 (13) :2882-2890
[4]   A new mononuclear Copper(II) complex containing two imidazolyl moieties as precursor of self-assembled and NiIICuIINiII heterobimetallic complexes [J].
Dominguez-Vera, JM ;
Camara, F ;
Moreno, JM ;
Colacio, E ;
Stoeckli-Evans, H .
INORGANIC CHEMISTRY, 1998, 37 (12) :3046-3050
[5]   A new method for incorporating thiolate donors into a metal coordination sphere.: synthesis and crystal structures of the first nickel complexes of an N3S ligand [J].
Goswami, N ;
Eichhorn, DM .
INORGANIC CHEMISTRY, 1999, 38 (19) :4329-4333
[6]   Coordination compounds of Schiff-base ligands derived from diaminomaleonitrile (DMN): Mononuclear, dinuclear, and macrocyclic derivatives [J].
MacLachlan, MJ ;
Park, MK ;
Thompson, LK .
INORGANIC CHEMISTRY, 1996, 35 (19) :5492-5499
[7]   Synthesis, characterization and crystal structures of some four coordinated nickel(II) complexes with tridentate Schiff base ligands [J].
Mondal, N ;
Mitra, S ;
Gramilich, V ;
Ghodsi, SO ;
Malik, KMA .
POLYHEDRON, 2001, 20 (1-2) :135-141
[8]  
Sheldrick G., 2017, SHELX2017, Programs for Crystal Structure Determination
[9]  
Sheldrick G.M., 1996, SADABS VERSION 2008
[10]  
Sheldrick G.M., 1997, SHELXTL VERSION 5 1