A practical enantioselective synthesis of massoialactone via hydrolytic kinetic resolution

被引：66

作者：

Gupta, P ^{[1
]}

Naidu, SV ^{[1
]}

Kumar, P ^{[1
]}

机构：

[1] Natl Chem Lab, Dept Organ Chem, Pune 411008, Maharashtra, India

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 04期

关键词：

D O I：

10.1016/j.tetlet.2003.11.032

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient enantioselective synthesis of (R)- and (S)-massoialactone has been achieved. The key steps are the hydrolytic kinetic resolution of a racemic epoxyheptane with (R,R)-(salen)-(CoOAc)-O-III complex and ring-closing metathesis of homoallylic alcohol derived acrylate esters using Grubb's catalyst. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：849 / 851

页数：3

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