The Ru(II)-supported heptatungstates [HXW7O28Ru(dmso)3]6- (X = P, As)

被引：57
作者：
Bi, LH
Dickman, MH
Kortz, U
Dix, I
机构：
[1] Int Univ Bremen, Sch Sci & Engn, D-28725 Bremen, Germany
[2] Bruker Analyt Xray Syst, D-76187 Karlsruhe, Germany
来源：
CHEMICAL COMMUNICATIONS | 2005年 / 31期
关键词：
D O I：
10.1039/b504903m
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The ruthenium(II)-supported heteropolyanions [HXW7O28-Ru(dmso)(3)](6-)(X = P, 1; As, 2) are composed of a Ru(dmso)(3) group attached to an unprecedented heptatungstate fragment via two Ru-O-W bonds and one Ru-O-X bond, which represents a fundamentally novel mode of Ru-coordination to a polyoxoanion framework. Multinuclear W-183, P-31, C-13, and H-1 NMR studies indicate high stability of 1 and 2 in solution.
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页码：3962 / 3964
页数：3
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