Catalytic hydrogenation of carboxylic acids using low-valent and high-valent metal complexes

被引：28

作者：

Yoshioka, Shota ^{[1
]}

Saito, Susumu ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 95期

关键词：

H BOND ACTIVATION; HOMOGENEOUS HYDROGENATION; CARBON-DIOXIDE; ASYMMETRIC HYDROGENATION; BUILDING-BLOCK; FATTY-ACIDS; RHENIUM; MECHANISM; CO2; METHANOL;

D O I：

10.1039/c8cc06543h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carboxylic acids are ubiquitous in bio-renewable and petrochemical sources of carbon. The hydrogenation of carboxylic acids to alcohols generates water as the only by-product, and thus represents a sustainable method for the production of these alternative energy carriers/platform chemicals on a large scale. Herein, we offer a brief account of the development of this new concept and molecular insights into cationic mononuclear low- and high-valent transition-metal complexes for the hydrogenation of carboxylic acids.

引用

页码：13319 / 13330

页数：13

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