Bare Magnetite-Promoted Oxidative Hydroxylation of Arylboronic Acids and Subsequent Conversion into Phenolic Compounds

被引：4
作者：
Cho, Hyun-A [1 ]
Lee, Yong-Ki [1 ]
Kim, Seung-Hoi [1 ]
机构：
[1] Dankook Univ, Dept Chem, Cheonan 31116, South Korea
来源：
SYNLETT | 2022年 / 33卷 / 13期
关键词：
magnetite; H2O2; ipso-hydroxylation; arylboronic acids; phenols; ARYL/HETEROARYL BORONIC ACIDS; HIGHLY EFFICIENT CONVERSION; IPSO-HYDROXYLATION; HETEROGENEOUS CATALYST; IONIC LIQUID; NANOPARTICLES; OXIDE; MILD; BASE; ESTERS;
D O I：
10.1055/s-0040-1719926
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The simple combination of readily available, recoverable, and recyclable magnetite (Fe3O4) nanoparticles and an environmentally friendly oxidant (H2O2) induced the effective functional group transformation of arylboronic acids into their corresponding phenols under mild conditions. Moreover, subsequent treatment of the reaction intermediate with appropriate electrophiles was accomplished in a one-pot system, leading to the formation of halophenols and phenolic derivatives.
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收藏
页码：1295 / 1301
页数：7
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