Correlating Pt-P bond lengths and Pt-P coupling constants

被引：44

作者：

Waddell, Paul G. ^{[1
]}

Slawin, Alexandra M. Z. ^{[1
]}

Woollins, J. Derek ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 37期

关键词：

NUCLEAR-MAGNETIC-RESONANCE; X-RAY-STRUCTURE; TERTIARY PHOSPHINE COMPLEXES; TRANSITION-METAL-COMPLEXES; SOLID-STATE STRUCTURES; PLATINUM(II) COMPLEXES; CRYSTAL-STRUCTURES; MOLECULAR-STRUCTURE; PHOSPHORUS LIGANDS; STACKING COMPOUNDS;

D O I：

10.1039/c003256e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The X-ray structures of (5) cis-PtBr2(P(OMe)(3))(2), (6) cis-PtBr2(P(OMe)(2)Ph)(2), (7) cis-PtBr2(P(OMe)Ph-2)(2), (8) cis-PtBr2(PPh3)(2), (9) cis-PtI2(P(OMe)(3))(2), (10) cis-PtI2(P(OMe)(2)Ph)(2), (11) cis-PtI2(P(OMe)Ph-2)(2) and (12) cis-PtI2(PPh3)(2) are reported and compared with the previously reported chloride analogues. The magnitude of the J{Pt-P} varies linearly with the Pt-P bond length (l(Pt-P) = 2.421 - J/24255) for these 12 complexes.

引用

页码：8620 / 8625

页数：6

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