In situ observation of a reversible single crystal-to-single-crystal apical-ligand exchange reaction in a hydrogen-bonded 2D coordination network

被引：152

作者：

Takaoka, K

Kawano, M

Tominaga, M

Fujita, M

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

[2] Genesis Res Inst Inc, Bunkyo Ku, Tokyo 1138656, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 14期

关键词：

cobalt; coordination polymers; host-guest systems; hydrogen bonds; ligand design;

D O I：

10.1002/anie.200462214

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Aqua and nitrate forms of a CoII center are reversibly interconverted within a square-grid complex because of flexible side chains attached to a rodlike ligand (see scheme; Co yellow, N blue, O red). The ligand exchange proceeds in a single-crystal-to-single-crystal fashion despite the drastic structural changes at the metal center. All processes are observed by in situ X-ray crystallography. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2151 / 2154

页数：4

共 50 条

[31] Operando single crystal neutron diffraction reveals insight into the field response mechanisms in the hydrogen-bonded KH2PO4 ferroelectric
Fancher, C. M.
Hoffmann, C. M.
Wang, X. P.
Daemen, L. L.
Schultz, A. J.
APL MATERIALS, 2021, 9 (02)
[32] Universal Strategy of 3D and 2D Hybrid Perovskites Single Crystal Growth via In Situ Solvent Conversion
Fateev, Sergey A.
Petrov, Andrey A.
Ordinartsev, Artem A.
Grishko, Alexey Y.
Goodilin, Eugene A.
Tarasov, Alexey B.
CHEMISTRY OF MATERIALS, 2020, 32 (22) : 9805 - 9812
[33] Temperature- and vapor-induced reversible single-crystal-to-single-crystal transformations of three 2D/3D GdIII-organic frameworks exhibiting significant magnetocaloric effects
Liu, Sui-Jun
Cao, Chen
Yao, Shu-Li
Zheng, Teng-Fei
Wang, Zheng-Xiang
Liu, Chao
Liao, Jin-Sheng
Chen, Jing-Lin
Li, Yun-Wu
Wen, He-Rui
DALTON TRANSACTIONS, 2017, 46 (01) : 64 - 70
[34] Ligand-Assisted Growth of 2D Perovskite Single Crystal for Highly Sensitive X-Ray Detectors
Feng, Xiaolong
Zhang, Lu
Zhang, Bobo
You, Jiaxue
Li, Kun
Zeng, Hanqing
Wang, Xiaofang
Dai, Zhonghua
Jia, Shilong
Bao, Haibo
Wang, Shujie
Liu, Shengzhong
ADVANCED FUNCTIONAL MATERIALS, 2024, 34 (37)
[35] Crystal structure and magnetic properties of [Fe{N(CN)2}2(MeOH)2] a 2-D layered network consisting of hydrogen-bonded l-D chains
Manson, JL
Arif, AM
Miller, JS
JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (04) : 979 - 983
[36] Cation Exchange-Induced Dimensionality Construction: From Monolayered to Multilayered 2D Single Crystal Halide Perovskites
Yu, Dejian
Cai, Bo
Cao, Fei
Li, Xiaoming
Liu, Xuhai
Zhu, Ying
Ji, Jianping
Gu, Yu
Zeng, Haibo
ADVANCED MATERIALS INTERFACES, 2017, 4 (19):
[37] Synthesis,Crystal Structure and Thermal Behavior of a New 2D Barium(Ⅱ) Coordination Polymer with 1H-benzimi-dazole-5,6-dicarboxylate as the Single Ligand
李琳
张玉涛
程劲松
赵荣飞
结构化学, 2011, 30 (04) : 563 - 567
[38] A 2D Hydrogen-Bonded 1D Coordination Network of Pr(III) with Pyridine-2,6-Dicarboxylic Acid: Hydrothermal Synthesis, Structure, and Luminescent Properties
Song, Shuang
Shao, Caiyun
Zhang, Huaimin
Zhang, Wu
Yang, Lirong
Ren, Tiegang
Bu, Zhanwei
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2013, 43 (02) : 169 - 174
[39] Single crystal-to-single crystal transformation - from two distinct to three distinct spin crossover centers in 2D coordination polymer [Fe(bbtr)3](CF3SO3)2
Ksiazek, Maria
Weselski, Marek
Kusz, Joachim
Bronisz, Robert
DALTON TRANSACTIONS, 2022, 51 (03) : 958 - 968
[40] Synthesis, Crystal Structure and Fluorescent Property of a 2D Network Zn(II) Coordination Polymer Based on Oxalic Acid and Bis(imidazol) Ligand
Zhan Pei-Ying
Ji Jian-Ye
Niu Yang-Ling
Wang Zhi-Tao
Li Xiu-Mei
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2013, 29 (02) : 424 - 428

← 1 2 3 4 5 →